1,4-Dihydro-r-4-methoxy-4-phenyl-t-1-(p-tolyl)arsenin

Base Information

• Chemical Name: 1,4-Dihydro-r-4-methoxy-4-phenyl-t-1-(p-tolyl)arsenin
• CAS No.: 63428-61-5
• Molecular Formula: C₁₉H₁₉AsO
• Molecular Weight: 338.281
• Mol file: 63428-61-5.mol

Synonyms:

Chemical Property of 1,4-Dihydro-r-4-methoxy-4-phenyl-t-1-(p-tolyl)arsenin

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1,4-Dihydro-r-4-methoxy-4-phenyl-t-1-(p-tolyl)arsenin

There total 5 articles about 1,4-Dihydro-r-4-methoxy-4-phenyl-t-1-(p-tolyl)arsenin which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

3-Phenyl-1,4-pentadiin-3-ol (27410-03-3) → 1,4-Dihydro-r-4-methoxy-4-phenyl-c-1-(p-tolyl)arsenin (63428-61-5,65683-85-4,65683-86-5)

Guidance literature:

Multi-step reaction with 2 steps

1: 78 percent / tetrabutylammonium iodide, 50percent NaOH / tetrahydrofuran / 1) 3 h, 45 deg C; 2) 1 h, reflux

2: KOH / <18>crown-6 / benzene / 3 h / Ambient temperature

With potassium hydroxide; sodium hydroxide; tetra-(n-butyl)ammonium iodide; 18-crown-6 ether; In tetrahydrofuran; benzene;

Reference yield:

3-Phenyl-1,4-pentadiin-3-ol (27410-03-3) → 1,4-Dihydro-r-4-methoxy-4-phenyl-t-1-(p-tolyl)arsenin (63428-61-5,65683-85-4,65683-86-5)

Guidance literature:

Multi-step reaction with 2 steps

1: 78 percent / tetrabutylammonium iodide, 50percent NaOH / tetrahydrofuran / 1) 3 h, 45 deg C; 2) 1 h, reflux

2: KOH / <18>crown-6 / benzene / 3 h / Ambient temperature

With potassium hydroxide; sodium hydroxide; tetra-(n-butyl)ammonium iodide; 18-crown-6 ether; In tetrahydrofuran; benzene;

Reference yield:

3-phenyl-3-methoxypenta-1,4-diyne (51110-57-7) + p-tolylarsine (65684-01-7) → 1,4-Dihydro-r-4-methoxy-4-phenyl-c-1-(p-tolyl)arsenin (63428-61-5,65683-85-4,65683-86-5) + 1,4-Dihydro-r-4-methoxy-4-phenyl-t-1-(p-tolyl)arsenin (63428-61-5,65683-85-4,65683-86-5)

Guidance literature:

With potassium hydroxide; 18-crown-6 ether; In benzene; for 3h; Yield given. Yields of byproduct given; Ambient temperature;

upstream raw materials:

3-phenyl-3-methoxypenta-1,4-diyne

p-tolylarsine

3-Phenyl-1,4-pentadiin-3-ol

Downstream raw materials:

4-Phenyl-2-(p-tolyl)arsenin

Refernces