51110-57-7

Upstream product

• 27410-03-3 3-Phenyl-1,4-pentadiin-3-ol 
• 77-78-1 dimethyl sulfate 
• 165055-35-6 1-trimethylsilyl-3-phenyl-3-methoxypenta-1,4-diyne 
• 13829-77-1 3-(trimethylsilyl)-1-phenyl-2-propyn-1-one 
• 98-88-4 benzoyl chloride 
• 99048-51-8 3-phenyl-1-(trimethylsilyl)penta-1,4-diyn-3-ol 

Downstream Products

• 63428-62-6 1,4-Dihydro-methoxy-1,4-diphenylarsenin 
• 65683-75-2 1,4-Dihydro-4-methoxy-1,4-diphenylphosphorin 
• 63428-61-5 1,4-Dihydro-4-methoxy-4-phenyl-1-(p-tolyl)arsenin 
• 63428-62-6 1,4-Dihydro-r-methoxy-c-1,4-diphenylarsenin 
• 63428-62-6 1,4-Dihydro-r-methoxy-t-1,4-diphenylarsenin 
• 63428-61-5 1,4-Dihydro-r-4-methoxy-4-phenyl-c-1-(p-tolyl)arsenin 
• 63428-61-5 1,4-Dihydro-r-4-methoxy-4-phenyl-t-1-(p-tolyl)arsenin 
• 51470-92-9 1,1-di-n-butyl-4-phenyl-4-methoxy-1,4-dihydrostannane 

Relevant academic research and scientific papers

Functional [6]pericyclynes: Synthesis through [14+4] and [8+10] cyclization strategies

Critical analysis of possible strategies for the synthesis of novel carbo-benzene derivatives suggests several [(18-n)+n] routes for the preparation of hexaoxy[6]pericyclyne precursors. Beyond the previously attempted [9 + 9] symmetrical scheme (n = 9), t

Synthesis and stereochemical resolution of functional [5]pericyclynes

Three different kinds of ring carbo-mers of [5]cyclitol ethers were targeted as challenging examples of functional [5]pericyclynes. Three tertiary pentaaryl-carbo-[5]cyclitol methyl ethers were synthesized through a [11+4] ring-closing double addition of

Synthesis of 2-Aryl-(2-R)-arsenines by Cyclohexadienol -> Arsabenzene Rearrangement

KOH/crown-6 phase-transfer catalyzed addition of arylarsines (phenylarsine, p-tolylarsine) to the (3-R)-3-methoxy-1,4-pentadiynes 13 yields the cis/trans isomeric 1-aryl-1,4-dihydro-(4-R)-4-methoxyarsenines, the 1H-NMR- and 13C-NMR spectra of which ar