Acetic acid (1S,2S,3R,4S)-3-benzhydryl-1,7,7-trimethyl-bicyclo[2.2.1]hept-2-yl ester

Base Information

Chemical Name:Acetic acid (1S,2S,3R,4S)-3-benzhydryl-1,7,7-trimethyl-bicyclo[2.2.1]hept-2-yl ester
CAS No.:479686-19-6
Molecular Formula:C₂₅H₃₀O₂
Molecular Weight:362.512
Hs Code.:

Synonyms:

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Chemical Property of Acetic acid (1S,2S,3R,4S)-3-benzhydryl-1,7,7-trimethyl-bicyclo[2.2.1]hept-2-yl ester

Chemical Property:

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Technology Process of Acetic acid (1S,2S,3R,4S)-3-benzhydryl-1,7,7-trimethyl-bicyclo[2.2.1]hept-2-yl ester

There total 14 articles about Acetic acid (1S,2S,3R,4S)-3-benzhydryl-1,7,7-trimethyl-bicyclo[2.2.1]hept-2-yl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 464-48-2,68546-28-1
(1S)-camphor

: 479686-19-6
Acetic acid (1S,2S,3R,4S)-3-benzhydryl-1,7,7-trimethyl-bicyclo[2.2.1]hept-2-yl ester

Guidance literature:: Multi-step reaction with 4 steps

1: n-BuLi / diethyl ether

2: TiCl₄ / CH₂Cl₂ / 1 h / -50 °C

3: LAH / tetrahydrofuran / 6 h / 20 °C

4: NaH / dioxane

With lithium aluminium tetrahydride; n-butyllithium; titanium tetrachloride; sodium hydride; In tetrahydrofuran; 1,4-dioxane; diethyl ether; dichloromethane;
DOI:10.1021/jo026183k

Reference yield:

: 464-45-9
endo-borneol

: 479686-19-6
Acetic acid (1S,2S,3R,4S)-3-benzhydryl-1,7,7-trimethyl-bicyclo[2.2.1]hept-2-yl ester

Guidance literature:: Multi-step reaction with 5 steps

1: n-BuLi / diethyl ether

2: TiCl₄ / CH₂Cl₂ / 1 h / -50 °C

3: LAH / tetrahydrofuran / 6 h / 20 °C

4: NaH / dioxane

With lithium aluminium tetrahydride; n-butyllithium; titanium tetrachloride; sodium hydride; In tetrahydrofuran; 1,4-dioxane; diethyl ether; dichloromethane; 1: Jones oxidation;
DOI:10.1021/jo026183k

Reference yield:

: 464-49-3,68546-28-1
(1R,4R)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-one

: 479686-19-6
Acetic acid (1S,2S,3R,4S)-3-benzhydryl-1,7,7-trimethyl-bicyclo[2.2.1]hept-2-yl ester

Guidance literature:: Multi-step reaction with 10 steps

1: n-BuLi / diethyl ether

2: TiCl₄ / CH₂Cl₂ / 1 h / -50 °C

3: 5.6 g / LAH / tetrahydrofuran / 6 h / 20 °C

4: 90 percent / NaH / dioxane

5: 98 percent / LDA / tetrahydrofuran; hexane / 1 h / -70 °C

6: 90 percent / KHSO₄ / xylene / 1.5 h / Heating

7: 68 percent / Et₄NOTs / acetonitrile / 20 °C / Electrolysis

8: 95 percent / LAH / tetrahydrofuran / 12 h / 20 °C

9: LAH / tetrahydrofuran / 6 h / 20 °C

10: NaH / dioxane

With potassium hydrogensulfate; lithium aluminium tetrahydride; n-butyllithium; titanium tetrachloride; sodium hydride; tetraethylammonium tosylate; lithium diisopropyl amide; In tetrahydrofuran; 1,4-dioxane; diethyl ether; hexane; dichloromethane; acetonitrile; xylene;
DOI:10.1021/jo026183k