DMAC-TRZ

Base Information

• Chemical Name: DMAC-TRZ
• CAS No.: 1628752-98-6
• Molecular Formula: C₃₆H₂₈N₄
• Molecular Weight: 516.645
• Mol file: 1628752-98-6.mol

Synonyms:

Chemical Property of DMAC-TRZ

Chemical Property:

• Boiling Point: 716.3±70.0 °C(Predicted)
• PKA: 0.93±0.10(Predicted)
• Density: 1.186±0.06 g/cm3(Predicted)

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of DMAC-TRZ

There total 7 articles about DMAC-TRZ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

9,9‐dimethyl‐10H‐acridine (6267-02-3) + 2-(4-bromobenzenyl)-4,6-diphenyl-1,3,5-triazine (23449-08-3) → 10-(4-(4,6-diphenyl-1,3,5-triazin-2-yl)phenyl) -9,9-dimethyl-9,10-dihydroacridine (1628752-98-6)

Guidance literature:

With tri-tert-butyl phosphine; palladium diacetate; potassium carbonate; In toluene; for 48h; Inert atmosphere; Reflux;

DOI:10.1039/c5cc05022g

Reference yield: 70.0%

2-chloro-4,6-diphenyl-1,3,5-triazine (3842-55-5) + 9,9-dimethyl-10-(4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl)-9.10-dihydroacridine (1643935-09-4) → 10-(4-(4,6-diphenyl-1,3,5-triazin-2-yl)phenyl) -9,9-dimethyl-9,10-dihydroacridine (1628752-98-6)

Guidance literature:

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; sodium carbonate; ammonium chloride; In water; toluene; at 100 ℃; for 16h; Inert atmosphere;

Reference yield:

Methyl N-phenylanthranilate (35708-19-1) → 10-(4-(4,6-diphenyl-1,3,5-triazin-2-yl)phenyl) -9,9-dimethyl-9,10-dihydroacridine (1628752-98-6)

Guidance literature:

Multi-step reaction with 5 steps

1: magnesium oxide / tetrahydrofuran / 20 °C / Inert atmosphere

2: phosphoric acid / 20 °C / Inert atmosphere

3: palladium diacetate; tri-tert-butyl phosphine; sodium t-butanolate / toluene / 12 h / Inert atmosphere; Reflux

4: 1,1'-bis-(diphenylphosphino)ferrocene; potassium acetate / toluene; 1,4-dioxane / 17 h / 120 °C / Inert atmosphere

5: sodium carbonate; ammonium chloride; tetrakis(triphenylphosphine) palladium⁽⁰⁾ / toluene; water / 16 h / 100 °C / Inert atmosphere

With 1,1'-bis-(diphenylphosphino)ferrocene; tetrakis(triphenylphosphine) palladium⁽⁰⁾; tri-tert-butyl phosphine; phosphoric acid; potassium acetate; palladium diacetate; magnesium oxide; sodium carbonate; ammonium chloride; sodium t-butanolate; In tetrahydrofuran; 1,4-dioxane; water; toluene;

upstream raw materials:

9,9‐dimethyl‐10H‐acridine

2-(4-bromobenzenyl)-4,6-diphenyl-1,3,5-triazine

Methyl N-phenylanthranilate

α,α-Dimethyl-2-(phenylamino)benzolmethanol

Refernces

• 1、 -. "Organic light emitting small-molecule material of spiral donor containing sulfuryl and preparation method thereof". Paragraph 0202-0206. . Retrieved 2018/12/14.
• 2、 Tsai, Wei-Lung,Huang, Ming-Hao,Lee, Wei-Kai,Hsu, Yi-Jiun,Pan, Kuan-Chung,Huang, Yi-Hsiang,Ting, Hao-Chun,Sarma, Monima,Ho, Yu-Yi,Hu, Hung-Chieh,Chen, Chung-Chia,Lee, Meng-Ting,Wong, Ken-Tsung,Wu, Chung-Chih. "A versatile thermally activated delayed fluorescence emitter for both highly efficient doped and non-doped organic light emitting devices". supporting information. p. 13662 - 13665. Retrieved 2015/09/01.