4,5-bis[5-(4-phenoxy)-10,15,20-triphenyl pophyrin]-1,2-dicarbonitrile zinc(II)

Base Information

Chemical Name:4,5-bis[5-(4-phenoxy)-10,15,20-triphenyl pophyrin]-1,2-dicarbonitrile zinc(II)
CAS No.:873077-01-1
Molecular Formula:C₉₆H₅₆N₁₀O₂Zn₂
Molecular Weight:1512.35
Hs Code.:

Synonyms:

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Chemical Property of 4,5-bis[5-(4-phenoxy)-10,15,20-triphenyl pophyrin]-1,2-dicarbonitrile zinc(II)

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Technology Process of 4,5-bis[5-(4-phenoxy)-10,15,20-triphenyl pophyrin]-1,2-dicarbonitrile zinc(II)

There total 2 articles about 4,5-bis[5-(4-phenoxy)-10,15,20-triphenyl pophyrin]-1,2-dicarbonitrile zinc(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

: zinc(II) acetate hydrate

: 4,5-bis[5-(4-phenoxy)-10,15,20-triphenyl pophyrin]-1,2-dicarbonitrile

: 873077-01-1
4,5-bis[5-(4-phenoxy)-10,15,20-triphenyl pophyrin]-1,2-dicarbonitrile zinc(II)

Guidance literature:: In N,N-dimethyl-formamide; mixt. Zn(OAc)2*nH2O and porphyrine in DMF was heated at 70°C for 1 h under N2 atm.; react. mixt. was cooled to room temp., poured into CH2Cl2,and washed with water, column chromy. on silica (CH2Cl2), soln. was evapd., residue was recrystd. from CH2Cl2-MeOH;
DOI:10.1039/b508478d

Reference yield:

: 4,5-bis[5-(4-phenoxy)-10,15,20-triphenyl pophyrin]-1,2-dicarbonitrile

: 557-34-6
zinc diacetate

: 873077-01-1
4,5-bis[5-(4-phenoxy)-10,15,20-triphenyl pophyrin]-1,2-dicarbonitrile zinc(II)

Guidance literature:: In N,N-dimethyl-formamide; at 70°C according to: Z. X. Zhao, T. Nyokong, D. Maree, Dalton Trans. 23 (2005) 3732-3737;
DOI:10.1016/j.saa.2007.07.010

Reference yield: 6.0%

: 873077-01-1
4,5-bis[5-(4-phenoxy)-10,15,20-triphenyl pophyrin]-1,2-dicarbonitrile zinc(II)

: 36530-06-0
subphthalocyanine

: 1036023-55-8
2,3-di-[5-(4-phenoxy)-10,15,20-triphenyl porphyrin zinc (II)] phthalocyanine

Guidance literature:: With 1,8-diazabicylo[5,4,0]undec-7-ene; In dimethyl sulfoxide; byproducts: porphyrin; heating of ClB(C8H4N2)3 in DMSO at 60°C for 2 h with stirring under N2; addn. of ((ZnC20H8N4Ph3C6H4O)2C6H2(CN)2 and DBU (2 drops); heating to 120°C for 24 h with stirring under N2; cooling to room temp., pouring into CH2Cl2; washing 3 times with H2O; collection of CH2Cl2 layer; evapn.; chromy.; eluting by CH2Cl2 and CH2Cl2 with 5% MeOH; evapn. of CH2Cl2 and MeOH; recrystn. from CH2Cl2 and MeOH;
DOI:10.1016/j.saa.2007.07.010