2,3-di-[5-(4-phenoxy)-10,15,20-triphenyl porphyrin zinc (II)] phthalocyanine

Base Information

• Chemical Name: 2,3-di-[5-(4-phenoxy)-10,15,20-triphenyl porphyrin zinc (II)] phthalocyanine
• CAS No.: 1036023-55-8
• Molecular Formula: C₁₂₀H₇₀N₁₆O₂Zn₂
• Molecular Weight: 1898.76
• Mol file: 1036023-55-8.mol

Synonyms:

Chemical Property of 2,3-di-[5-(4-phenoxy)-10,15,20-triphenyl porphyrin zinc (II)] phthalocyanine

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2,3-di-[5-(4-phenoxy)-10,15,20-triphenyl porphyrin zinc (II)] phthalocyanine

There total 1 articles about 2,3-di-[5-(4-phenoxy)-10,15,20-triphenyl porphyrin zinc (II)] phthalocyanine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 6.0%

4,5-bis[5-(4-phenoxy)-10,15,20-triphenyl pophyrin]-1,2-dicarbonitrile zinc(II) (873077-01-1) + subphthalocyanine (36530-06-0) → 2,3-di-[5-(4-phenoxy)-10,15,20-triphenyl porphyrin zinc (II)] phthalocyanine (1036023-55-8)

Guidance literature:

With 1,8-diazabicylo[5,4,0]undec-7-ene; In dimethyl sulfoxide; byproducts: porphyrin; heating of ClB(C8H4N2)3 in DMSO at 60°C for 2 h with stirring under N2; addn. of ((ZnC20H8N4Ph3C6H4O)2C6H2(CN)2 and DBU (2 drops); heating to 120°C for 24 h with stirring under N2; cooling to room temp., pouring into CH2Cl2; washing 3 times with H2O; collection of CH2Cl2 layer; evapn.; chromy.; eluting by CH2Cl2 and CH2Cl2 with 5% MeOH; evapn. of CH2Cl2 and MeOH; recrystn. from CH2Cl2 and MeOH;

DOI:10.1016/j.saa.2007.07.010

Reference yield: 91.0%

2,3-di-[5-(4-phenoxy)-10,15,20-triphenyl porphyrin zinc (II)] phthalocyanine (1036023-55-8) + zinc diacetate (557-34-6) → 2,3-di-[5-(4-phenoxy)-10,15,20-triphenyl porphyrin zinc (II)] phthalocyanine zinc(II)

Guidance literature:

In N,N-dimethyl-formamide; byproducts: acetic acid; heating of mixt. of (ZnC20H8N4Ph3C6H4O)2C32H16N8 and Zn(CH3COO)2 in DMF at 70°C for 1 h with stirring under N2; cooling to room temp., pouring into CH2Cl2; washing 3 times with H2O; chromy. on silica gel with CH2Cl2 + 5% MeOH; evapn., recrystn. from CH2Cl2with MeOH;

DOI:10.1016/j.saa.2007.07.010

upstream raw materials:

4,5-bis[5-(4-phenoxy)-10,15,20-triphenyl pophyrin]-1,2-dicarbonitrile zinc(II)

subphthalocyanine