(C₆H₅)4P⁽¹⁺⁾*[MoS₃(OSi(CH₃)3)]^(1-)=((C₆H₅)4P)[MoS₃(OSi(CH₃)3)]

Base Information

Chemical Name:(C₆H₅)4P⁽¹⁺⁾*[MoS₃(OSi(CH₃)3)]^(1-)=((C₆H₅)4P)[MoS₃(OSi(CH₃)3)]
CAS No.:96211-55-1
Molecular Formula:C₃H₉MoOS₃Si*C₂₄H₂₀P
Molecular Weight:620.724
Hs Code.:

(C<sub>6</sub>H<sub>5</sub>)4P<sup>(1+)</sup>*[MoS<sub>3</sub>(OSi(CH<sub>3</sub>)3)]<sup>(1-)</sup>=((C<sub>6</sub>H<sub>5</sub>)4P)[MoS<sub>3</sub>(OSi(CH<sub>3</sub>)3)]

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Chemical Property of (C₆H₅)4P⁽¹⁺⁾*[MoS₃(OSi(CH₃)3)]^(1-)=((C₆H₅)4P)[MoS₃(OSi(CH₃)3)]

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Technology Process of (C₆H₅)4P⁽¹⁺⁾*[MoS₃(OSi(CH₃)3)]^(1-)=((C₆H₅)4P)[MoS₃(OSi(CH₃)3)]

There total 2 articles about (C₆H₅)4P⁽¹⁺⁾*[MoS₃(OSi(CH₃)3)]^(1-)=((C₆H₅)4P)[MoS₃(OSi(CH₃)3)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 47.0%

: 75-77-4
chloro-trimethyl-silane

: tetraphenylphosphonium trithiomolybdate

: 96211-55-1
(C₆H₅)4P⁽¹⁺⁾*[MoS₃(OSi(CH₃)3)]^(1-)=((C₆H₅)4P)[MoS₃(OSi(CH₃)3)]

Guidance literature:: In tetrahydrofuran; under N2; THF suspn. of (PPh4)2(MoOS3) treated with Me3SiCl (molar ratio1:1) at -80°C; stirred at -50°C for 36 h; solvent removed under reduced pressure; extd. with THF; extract centrifuged; soln. concd.; crystd. by slow diffusion of ether; elem. anal.;
DOI:10.1021/ic702397j

Reference yield: 31.0%

: di(tetra-n-butylammonium) dimolybdate

: 3385-94-2
hexamethyldisilathiane

: 13485-51-3
tetraphenylphosphonium nitrate

: 96211-55-1
(C₆H₅)4P⁽¹⁺⁾*[MoS₃(OSi(CH₃)3)]^(1-)=((C₆H₅)4P)[MoS₃(OSi(CH₃)3)]

Guidance literature:: In acetone; acetonitrile; a soln. of (Bu4N)2(Mo2O7) and (Me3Si)2S in MeCN were mixed and stirred for 24 h at room temp., solvent was removed and residue was treated withsoln. of (Ph4P)NO3 in acetone, after stirring for 30 min solvent was removed; EtOH was added to the mixt., ppt. was filtered, washed with ether/EtOH and ether, ppt. was dissolved in acetone and ether was added, soln. was maintained at -20°C for 2 h and filtered, filtrate was treated with ether and stored at -20°C;

Reference yield: 73.0%

: 75-77-4
chloro-trimethyl-silane

: 96211-55-1
(C₆H₅)4P⁽¹⁺⁾*[MoS₃(OSi(CH₃)3)]^(1-)=((C₆H₅)4P)[MoS₃(OSi(CH₃)3)]

: tetraphenylphosphonium trithio-chloro molybdate

Guidance literature:: In tetrahydrofuran; under N2; Me3SiCl added to THF soln. of (PPh4)(MoS3(OSiMe3)) (molar ratio 1:1) at room temp.; stirred for 30 min; centrifuged; soln. evapd. to dryness; extd. with THF; extract centrifuged; soln. evapd. under reduced pressure; washed with ether; dried under reduced pressure;
DOI:10.1021/ic702397j