((phenyl)(vinyl)chlorophosphine)W(CO)5

Base Information

• Chemical Name: ((phenyl)(vinyl)chlorophosphine)W(CO)5
• CAS No.: 101078-19-7
• Molecular Formula: C₁₃H₈ClO₅PW
• Molecular Weight: 494.48
• Mol file: 101078-19-7.mol

Synonyms:

Chemical Property of ((phenyl)(vinyl)chlorophosphine)W(CO)5

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of ((phenyl)(vinyl)chlorophosphine)W(CO)5

There total 1 articles about ((phenyl)(vinyl)chlorophosphine)W(CO)5 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(CO)5W{PhP(NEt2)(CHCH2)} (101078-12-0) → ((phenyl)(vinyl)chlorophosphine)W(CO)5 (101078-19-7)

Guidance literature:

With hydrogenchloride; In benzene; bubbling of gaseous HCl through the soln. of W compd. in benzene for 10 min; filtn. and evapn.;

DOI:10.1021/om00094a027

Reference yield: 80.0%

((phenyl)(vinyl)chlorophosphine)W(CO)5 (101078-19-7) → (CO)5WP(H)(Ph)CHCH2 (101078-14-2)

Guidance literature:

With HCl; LiAlH₄; In diethyl ether; benzene; LiAlH4, Et2O/C6H6, 25°C; HCl (2 N); chromy. on silica-gel (hexane/toluene);

Reference yield: 68.0%

cyclopentadienyl iron(II) dicarbonyl dimer (38117-54-3) + ((phenyl)(vinyl)chlorophosphine)W(CO)5 (101078-19-7) → (CO)5W{μ2-(Ph)vinylphosphido}Fe(CO)2(cyclopentadienyl) (112712-71-7)

Guidance literature:

In toluene; heating of the W compd. and the Fe compd. in toluene with stirring to 110°C for 1h under oxygen-free Ar; filtn., evapn. (vacuum), chromy. (elution with hexane-toluene) and recrystn. from hexane-toluene; elem. anal.;

DOI:10.1021/om00094a027

upstream raw materials:

(CO)5W{PhP(NEt₂)(CHCH₂)}

Downstream raw materials:

(OC)5W(PhPEtH)

(CO)5WP(H)(Ph)CHCH₂

(CO)5W{μ2-(Ph)vinylphosphido}Fe(CO)2(cyclopentadienyl)