Gallium, dimethyl-

Base Information

• Chemical Name: Gallium, dimethyl-
• CAS No.: 106693-86-1
• Molecular Formula: C2H6Ga
• Molecular Weight: 99.7926
• DSSTox Substance ID: DTXSID10422658
• Mol file: 106693-86-1.mol

Synonyms:Gallium, dimethyl-;dimethylgallane;106693-86-1;DTXSID10422658

Chemical Property of Gallium, dimethyl-

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 98.97252
• Heavy Atom Count: 3
• Complexity: 2.8

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C[Ga]C

Technology Process of Gallium, dimethyl-

There total 1 articles about Gallium, dimethyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

trimethyl gallium (1445-79-0) → gallium (7440-55-3) + monomethyl gallium (99601-83-9) + dimethylgallium (106693-86-1)

Guidance literature:

In gas; byproducts: CH3, C2H6; Irradiation (UV/VIS); laser photolysis;

DOI:10.1016/0009-2614(90)85050-M

Reference yield: 85.0%

dimethylgallium (106693-86-1) + 1,3,5,7,9,11,14-heptacyclopentyl-14-(methyl-diphenyl-silanyloxy)-2,4,6,8,10,12,13,15,16-nonaoxa-1,3,5,7,9,11,14-heptasila-tricyclo[7.3.3.15,11]hexadecane-3,7-diol (634203-31-9) → [(C5H9)7Si7O11(OSiCH3(C6H5)2)Ga(CH3)]2

Guidance literature:

In toluene; GaMe2 in toluene was added to cooled (-80°C) toluene soln. of Ga-complex, warmed to room temp., refluxed overnight under Ar; volatiles were evapd., dissolved in hexane, filtered, concd., cooled; elem. anal.;

Reference yield: 72.0%

dimethylgallium (106693-86-1) + 1,3,5,7,9,11,14-heptacyclopentyl-14-(methyl-diphenyl-silanyloxy)-2,4,6,8,10,12,13,15,16-nonaoxa-1,3,5,7,9,11,14-heptasila-tricyclo[7.3.3.15,11]hexadecane-3,7-diol (634203-31-9) → 2(C5H9)7Si7O11(OSiCH3(C6H5)2)(2-)*4Ga(3+)*8(CH3)(1-)=[(C5H9)7Si7O11(OSiCH3(C6H5)2)]2(Ga(CH3)2)4

Guidance literature:

In toluene; GaMe2 in toluene was added to cooled (-80°C) toluene soln. of Ga-complex, warmed to room temp., stirred for 30 min under Ar, refluxed for1 min; volatiles were evapd., hexane was added, evapd., recrystd. from hot hexane; elem. anal.;

upstream raw materials:

trimethyl gallium