[RuCl2(PPh3)(η6-PhMe)]

Base Information

• Chemical Name: [RuCl2(PPh3)(η6-PhMe)]
• CAS No.: 936566-07-3
• Molecular Formula: C₂₅H₂₃Cl₂PRu
• Molecular Weight: 526.407
• Mol file: 936566-07-3.mol

Synonyms:

Chemical Property of [RuCl2(PPh3)(η6-PhMe)]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [RuCl2(PPh3)(η6-PhMe)]

There total 1 articles about [RuCl2(PPh3)(η6-PhMe)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

bis[dichlorido(η6-toluene)ruthenium(II)] (52462-27-8) + triphenylphosphine (603-35-0) → [RuCl2(PPh3)(η6-PhMe)] (936566-07-3)

Guidance literature:

In dichloromethane; under N2 atm. to soln. Ru complex and PPh3 in was stirred at room temp. for 90 min; hexane was added, ppt. was washed with Et2O and pentane; elem. anal.;

DOI:10.1021/om070050d

Reference yield: 85.0%

ammonium hexafluorophosphate + [RuCl2(PPh3)(η6-PhMe)] (936566-07-3) + acetonitrile (75-05-8,26809-02-9) → [RuCl(NCMe)(PPh3)(η6-PhMe)]PF6 (936566-02-8)

Guidance literature:

In acetonitrile; under N2 atm. suspn. Ru complex and (NH4)PF6 in MeCN was heated at reflux for 2 h; soln. was cooled to room temp., solvent was removed in vacuo, residue was extd. with CH2Cl2 through Celite, recrystn. from CH2Cl2-Et2O;

DOI:10.1021/om070050d

Reference yield: 69.0%

ammonium hexafluorophosphate + dichloromethane (75-09-2) + [RuCl2(PPh3)(η6-PhMe)] (936566-07-3) + triphenylphosphine (603-35-0) → [RuCl(PPh3)2(η6-PhMe)]PF6*1/2CH2Cl2

Guidance literature:

In methanol; dichloromethane; under N2 atm. soln. Ru complex, PPh3 and (NH4)PF6 in MeOH-CH2Cl2 (1:1) was stirred at 35°C for 2 h and at 50°C for 2 h; soln. was concd., residue was washed with EtOH and Et2O;

DOI:10.1021/om070050d

upstream raw materials:

bis[dichlorido(η6-toluene)ruthenium(II)]

triphenylphosphine

Downstream raw materials:

[RuCl(NCMe)(PPh3)(η6-PhMe)]PF6