trichloro[2-(5,6-diphenyl-1,2,4-triazin-3-yl-κN2)-1,10-phenanthroline-κN1,κN10]ruthenium

Base Information

• Chemical Name: trichloro[2-(5,6-diphenyl-1,2,4-triazin-3-yl-κN2)-1,10-phenanthroline-κN1,κN10]ruthenium
• CAS No.: 683764-37-6
• Molecular Formula: C₂₇H₁₇Cl₃N₅Ru
• Molecular Weight: 618.894
• Mol file: 683764-37-6.mol

Synonyms:

Chemical Property of trichloro[2-(5,6-diphenyl-1,2,4-triazin-3-yl-κN2)-1,10-phenanthroline-κN1,κN10]ruthenium

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of trichloro[2-(5,6-diphenyl-1,2,4-triazin-3-yl-κN2)-1,10-phenanthroline-κN1,κN10]ruthenium

There total 1 articles about trichloro[2-(5,6-diphenyl-1,2,4-triazin-3-yl-κN2)-1,10-phenanthroline-κN1,κN10]ruthenium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.3%

ruthenium trichloride hydrate (14898-67-0) + 3-(2-(1,10-phenanthrolyl))-5,6-diphenyl-1,2,4-triazine (87209-05-0) → trichloro[2-(5,6-diphenyl-1,2,4-triazin-3-yl-κN2)-1,10-phenanthroline-κN1,κN10]ruthenium (683764-37-6)

Guidance literature:

In ethanol; soln. of RuCl3*nH2O and triazine derivative in abs. ethanol heated underreflux for 3 h; cooled to room temp., ppt. filtered off, washed 3 times with abs. EtOH and 3 times with Et2O, dried in air; elem. anal.;

DOI:10.1016/j.poly.2003.11.055

Reference yield: 65.0%

bis(3-aminopropyl)amine (56-18-8) + trichloro[2-(5,6-diphenyl-1,2,4-triazin-3-yl-κN2)-1,10-phenanthroline-κN1,κN10]ruthenium (683764-37-6) + sodium perchlorate → (N-[3-(amino-κN)propyl]propane-1,3-diamine-κN,κN')[2-(5,6-diphenyl-1,2,4-triazin-3-yl-κN2)-1,10-phenanthroline-κN1,κN10]ruthenium(2+) diperchlorate

Guidance literature:

With triethyl amine; In ethanol; water; a mixt. of complex, triamine and (C2H5)3N in ethanol-water 1:1 was refluxed for 8 h, cooled to room temp., evapd., satd. aq. NaClO4 was added; column chromy. (neutral alumina, CH3CN/ethanol); elem. anal.;

DOI:10.1002/hlca.200490108

Reference yield: 63.0%

trichloro[2-(5,6-diphenyl-1,2,4-triazin-3-yl-κN2)-1,10-phenanthroline-κN1,κN10]ruthenium (683764-37-6) + sodium perchlorate + water (7732-18-5) + 3-azapentane-1,5-diamine (111-40-0,98824-35-2) → Ru(3-(1,10-phenanthroline-2-yl)-5,6-diphenyl-as-triazine)(diethylenetriamine)(ClO4)2*2H2O

Guidance literature:

With triethyl amine; In ethanol; water; mixt. of diethylenetriamine, Ru-complex, and Et3N in EtOH/H2O (1/1 (v/v)) heated under reflux for 8 h, EtOH removed under vac. at room temp., aq. NaClO4 added; ppt. collected, column chromy. (alumina, MeCN); elem. anal.;

DOI:10.1016/j.poly.2003.11.055

upstream raw materials:

ruthenium trichloride hydrate

3-(2-(1,10-phenanthrolyl))-5,6-diphenyl-1,2,4-triazine