bis(N-phenyl-o-phenylenediamino)tetra(μ2-pivalato)dirhodium(II) toluene monosolvate

Base Information

Chemical Name:bis(N-phenyl-o-phenylenediamino)tetra(μ2-pivalato)dirhodium(II) toluene monosolvate
CAS No.:874961-43-0
Molecular Formula:C₇H₈*C₄₄H₆₀N₄O₈Rh₂
Molecular Weight:1070.93
Hs Code.:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of bis(N-phenyl-o-phenylenediamino)tetra(μ2-pivalato)dirhodium(II) toluene monosolvate

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Technology Process of bis(N-phenyl-o-phenylenediamino)tetra(μ2-pivalato)dirhodium(II) toluene monosolvate

There total 1 articles about bis(N-phenyl-o-phenylenediamino)tetra(μ2-pivalato)dirhodium(II) toluene monosolvate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

: 70084-27-4
[Rh₂(trimethylacetate)₄(H₂O)₂]

: 108-88-3,15644-74-3,16713-13-6
toluene

: 534-85-0
N-phenyl-1,2-benzenediamine

: 874961-43-0
bis(N-phenyl-o-phenylenediamino)tetra(μ2-pivalato)dirhodium(II) toluene monosolvate

Guidance literature:: In toluene; dissolving of mixt. of Rh(H2O)2(Me3CCOO)4 and N-phenyl-o-phenylenediamine (2 equiv.) in toluene under Ar at 50-80°C; concn. at 0.1 Torr (50°C); cooling to 5°C; crystn., decanting, washing with toluene, drying in air; elem. anal.;
DOI:10.1007/s11172-005-0293-5

Reference yield: 65.0%

: 39604-60-9
pyrrole-2,5-biscarboxaldehyde

: 874961-43-0
bis(N-phenyl-o-phenylenediamino)tetra(μ2-pivalato)dirhodium(II) toluene monosolvate

: 71-43-2,26181-88-4,54682-86-9,13967-78-7,174973-66-1
benzene

: di(5-(1-phenyl-1H-benzimidazol-2-yl)-1H-pyrrole-2-carbaldehydo)-tetra(μ2-pivalato)dirhodium(II) benzene pentasolvate

Guidance literature:: In benzene; dissolving of Rh2(Me3CCOO)4(NH2C6H4NHPh)2 in benzene under Ar; addn. of pyrrole-2,5-dialdehyde; heating at 80°C for 20 min; concn., cooling to 20°C, crystn. for 48 h; filtration, washing with cold hexane, drying in vac., elem. anal.;
DOI:10.1007/s11172-005-0293-5