Benzene, 1-chloro-4-(ethenyloxy)-

Base Information

• Chemical Name: Benzene, 1-chloro-4-(ethenyloxy)-
• CAS No.: 1074-56-2
• Molecular Formula: C8H7ClO
• Molecular Weight: 154.596
• Hs Code.: 2909309090
• DSSTox Substance ID: DTXSID00464648
• Nikkaji Number: J150.170D
• Wikidata: Q82290058
• Mol file: 1074-56-2.mol

Synonyms:Benzene, 1-chloro-4-(ethenyloxy)-;1074-56-2;1-chloro-4-ethenoxybenzene;4-CHLOROPHENYLVINYLETHER;p-chlorophenyl vinyl ether;1-Chloro-4-vinyloxy-benzene;SCHEMBL194685;SCHEMBL12139379;DTXSID00464648;AKOS015713464

Chemical Property of Benzene, 1-chloro-4-(ethenyloxy)-

Chemical Property:

• PSA: 9.23000
• LogP: 2.86230
• XLogP3: 3.3
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 2
• Exact Mass: 154.0185425
• Heavy Atom Count: 10
• Complexity: 106

Purity/Quality:

98%,99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C=COC1=CC=C(C=C1)Cl

Technology Process of Benzene, 1-chloro-4-(ethenyloxy)-

There total 13 articles about Benzene, 1-chloro-4-(ethenyloxy)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

4-chloro-phenol (106-48-9,82344-39-6) + 2,4,6-trivinylcyclotriboroxane*pyridine complex → p-chlorophenyl vinyl ether (1074-56-2)

Guidance literature:

With pyridine; copper diacetate; In dichloromethane; at 20 ℃; for 24h;

DOI:10.1021/jo049314l

Reference yield: 63.0%

1-(2-bromoethoxy)-4-chlorobenzene (2033-76-3) → p-chlorophenyl vinyl ether (1074-56-2)

Guidance literature:

With potassium tert-butylate; In dimethyl sulfoxide; at 20 ℃; for 2h; Inert atmosphere;

DOI:10.1039/d1cc04619e

Reference yield: 56.0%

3-(4-chlorophenoxy)propionic acid (3284-79-5) → p-chlorophenyl vinyl ether (1074-56-2)

Guidance literature:

With 2,2-dimethylpropanoic anhydride; bis[2-(diphenylphosphino)phenyl] ether; palladium dichloride; In various solvent(s); at 110 ℃; for 16h;

DOI:10.1039/b316613a

upstream raw materials:

1-(2-bromoethoxy)-4-chlorobenzene

chloroethylene

sodium 4-chlorophenolate

4-chloro-phenol

Downstream raw materials:

4-chloro-1-α-chloroethoxybenzene

(4-Chlor-phenyl)-(1,2-dichlor-aethyl)-aether

1,1,2,2-Tetracyano-3-(4'-chloro)-phenoxycyclobutan

1-Chloro-4-(1-chloro-2-thiocyanato-ethoxy)-benzene