tricarbonylbis(triphenylphosphine)iridium hexafluorophosphate

Base Information

• Chemical Name: tricarbonylbis(triphenylphosphine)iridium hexafluorophosphate
• CAS No.: 50520-11-1
• Molecular Formula: C₃₉H₃₀IrO₃P₂*F₆P
• Molecular Weight: 945.797
• Mol file: 50520-11-1.mol

Synonyms:

Chemical Property of tricarbonylbis(triphenylphosphine)iridium hexafluorophosphate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of tricarbonylbis(triphenylphosphine)iridium hexafluorophosphate

There total 4 articles about tricarbonylbis(triphenylphosphine)iridium hexafluorophosphate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(P(C6H5)3)2Ir(H)(SC4H5)(1+)*PF6(1-)=((P(C6H5)3)2Ir(H)(SC4H5))PF6 → tricarbonylbis(triphenylphosphine)iridium hexafluorophosphate (50520-11-1)

Guidance literature:

With CO; In chloroform-d1; byproducts: 2,5-dihydrothiophene, 2,3-dihydrothiophene; bubbling a stream of CO through a CDCl3 soln. of Ir-complex for 24 h at room temp.; transferring into NMR tube, detected by (1)H- and (31)P-NMR;

DOI:10.1021/om00014a050

Reference yield:

dicarbonylbis(triphenylphosphine)dihydridoiridium hexafluorophosphate (19392-91-7) + carbon monoxide (201230-82-2) → tricarbonylbis(triphenylphosphine)iridium hexafluorophosphate (50520-11-1)

Guidance literature:

With 1-hexene; In benzene; byproducts: aldehyde-C7; heated under CO at 100°C for 1 h; evapd. to dryness; IR, gas-chromy.; Kinetics;

DOI:10.1016/j.molcata.2007.01.045

Reference yield:

(P(C6H5)3)2Ir(H)(SC4H5)(1+)*PF6(1-)=((P(C6H5)3)2Ir(H)(SC4H5))PF6 → tricarbonylbis(triphenylphosphine)iridium hexafluorophosphate (50520-11-1) + carbonylbis(triphenylphosphine)(η2-C3,S-2H-thiophene)hydridoiridium hexafluorophosphate + carbonylbis(triphenylphosphine)(η2-C5,S-2H-thiophene)hydridoiridium hexafluorophosphate

Guidance literature:

With CO; hexamethyldisiloxane; In chloroform-d1; byproducts: 2,3-dihydrothiophene, 2,5-dihydrothiophene; heating a soln. of Ir-complex in CDCl3 at 50°C under a slow stream of CO for 30 min; transferring into NMR tube, detected by (1)H- and (31)P-NMR;

DOI:10.1021/om00014a050

upstream raw materials:

(η4-1,5-cyclooctadiene)bis(triphenylphosphine)iridium hexafluorophosphate

carbon monoxide

dicarbonylbis(triphenylphosphine)dihydridoiridium hexafluorophosphate

Downstream raw materials:

HIr(PPh₃)2(CO)2

trans-[Ir(CO)2(PPh₃)2]PF₆

IrH(C₂C₆H₅)(CO)2(P(C₆H₅)3)2⁽¹⁺⁾*PF₆^(1-)=[IrH(C₂C₆H₅)(CO)2(P(C₆H₅)3)2]PF₆

dicarbonylbis(triphenylphosphine)dihydridoiridium hexafluorophosphate