dicarbonylbis(triphenylphosphine)dihydridoiridium hexafluorophosphate

Base Information

Chemical Name:dicarbonylbis(triphenylphosphine)dihydridoiridium hexafluorophosphate
CAS No.:19392-91-7
Molecular Formula:C₃₈H₃₂IrO₂P₂*F₆P
Molecular Weight:919.803
Hs Code.:

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Chemical Property of dicarbonylbis(triphenylphosphine)dihydridoiridium hexafluorophosphate

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Technology Process of dicarbonylbis(triphenylphosphine)dihydridoiridium hexafluorophosphate

There total 8 articles about dicarbonylbis(triphenylphosphine)dihydridoiridium hexafluorophosphate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 150468-39-6
bis(η1-thiophene)dihydridobis(triphenylphosphine)iridium hexafluorophosphate

: 19392-91-7
dicarbonylbis(triphenylphosphine)dihydridoiridium hexafluorophosphate

Guidance literature:: Multi-step reaction with 3 steps

1: chloroform-d1

2: CO / chloroform

3: H₂; CO / chloroform

With CO; H₂; In chloroform-d1; chloroform;
DOI:10.1021/om00014a050

Reference yield:

: 65804-43-5,73209-98-0
[Ir(H)₂(PPh₃)₂(Me₂CO)₂]PF₆

: 19392-91-7
dicarbonylbis(triphenylphosphine)dihydridoiridium hexafluorophosphate

Guidance literature:: Multi-step reaction with 4 steps

1: chloroform

2: H₂ / 1,2-dichloro-ethane

3: CO / chloroform

4: H₂; CO / chloroform

With H₂; CO; In chloroform; 1,2-dichloro-ethane;
DOI:10.1021/om00014a050

Reference yield:

: carbonylbis(triphenylphosphine)(η1-tetrahydrothiophene)dihydridoiridium hexafluorophosphate

: 19392-91-7
dicarbonylbis(triphenylphosphine)dihydridoiridium hexafluorophosphate

Guidance literature:: With H₂; CO; In chloroform; bubbling a 1:1 mixt. of CO/H2 through a soln. of Ir-complex in CHCl3 at 60°C for 3 h; removal of solvent in vacuo, detected by NMR spectroscopy;
DOI:10.1021/om00014a050