[(3,4,5-F₃C₆H₂NCH₂CH₂)2NMe]TaMe₃

Base Information

• Chemical Name: [(3,4,5-F₃C₆H₂NCH₂CH₂)2NMe]TaMe₃
• CAS No.: 919479-88-2
• Molecular Formula: C₂₀H₂₄F₆N₃Ta
• Molecular Weight: 601.369
• Mol file: 919479-88-2.mol

Synonyms:

Chemical Property of [(3,4,5-F₃C₆H₂NCH₂CH₂)2NMe]TaMe₃

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [(3,4,5-F₃C₆H₂NCH₂CH₂)2NMe]TaMe₃

There total 1 articles about [(3,4,5-F₃C₆H₂NCH₂CH₂)2NMe]TaMe₃ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

[(3,4,5-F3C6H2NCH2CH2)2NMe]TaCl3 (919479-87-1) + methylmagnesium chloride (676-58-4) → [(3,4,5-F3C6H2NCH2CH2)2NMe]TaMe3 (919479-88-2)

Guidance literature:

In tetrahydrofuran; diethyl ether; CH3MgCl in THF added to a suspn. of Ta complex in Et2O at -30°C, allowed to warm to room temp., reacted for 1 h; 1,4-dioxane added, filtered, concd. (vac.), rinsed with pentane, dried (vac.); elem. anal.;

DOI:10.1016/j.ica.2006.03.044

Reference yield: 99.0%

[(3,4,5-F3C6H2NCH2CH2)2NMe]TaMe3 (919479-88-2) + tris(pentafluorophenyl)borate (1109-15-5) → [[(3,4,5-F3C6H2NCH2CH2)2NMe]TaMe2][MeB(C6F5)3] (919479-90-6)

Guidance literature:

In dichloromethane; B(C6F5)3 added to a soln. of Ta complex at -30°C, allowed to warmto room temp., reacted for 15 min; evapd. (vac.), triturated with pentane, filtered off, dried (vac.); elem. anal.;

DOI:10.1016/j.ica.2006.03.044

upstream raw materials:

[(3,4,5-F₃C₆H₂NCH₂CH₂)2NMe]TaCl₃

methylmagnesium chloride

Downstream raw materials:

[[(3,4,5-F₃C₆H₂NCH₂CH₂)2NMe]TaMe₂][MeB(C₆F₅)3]