C₆H₅CH₂CH₂C(SC₆H₅)(Sn(C₄H₉)3)(CH(CH₃)C(O)CH₂CH₃)

Base Information

• Chemical Name: C₆H₅CH₂CH₂C(SC₆H₅)(Sn(C₄H₉)3)(CH(CH₃)C(O)CH₂CH₃)
• CAS No.: 164401-10-9
• Molecular Formula: C₃₂H₅₀OSSn
• Molecular Weight: 601.524
• Mol file: 164401-10-9.mol

Synonyms:

Chemical Property of C₆H₅CH₂CH₂C(SC₆H₅)(Sn(C₄H₉)3)(CH(CH₃)C(O)CH₂CH₃)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₆H₅CH₂CH₂C(SC₆H₅)(Sn(C₄H₉)3)(CH(CH₃)C(O)CH₂CH₃)

There total 1 articles about C₆H₅CH₂CH₂C(SC₆H₅)(Sn(C₄H₉)3)(CH(CH₃)C(O)CH₂CH₃) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 69.0%

3-phenyl-1,1-bis(phenylthio)-1-tributylstannylpropane (142073-43-6) + 3-trimethylsilyloxy-2-pentene (17510-47-3) + tin(IV) chloride (7646-78-8) → C6H5CH2CH2C(SC6H5)(Sn(C4H9)3)(CH(CH3)C(O)CH2CH3) (164401-10-9)

Guidance literature:

In dichloromethane; to a CH2Cl2 solution of the α-tributylstannylthioacetal and the silyl-compound was added SnCl4 in CH2Cl2 at -78°C; stirring for 3,5 h; addition of water; extraction with CH2Cl2; dried (Na2SO4); condensed under reduced pressure; residue was purified by silica-gel chromatography (hexane:AcOEt = 98:2); IR, NMR;

DOI:10.1246/cl.1992.819

upstream raw materials:

3-phenyl-1,1-bis(phenylthio)-1-tributylstannylpropane

3-trimethylsilyloxy-2-pentene

tin(IV) chloride