RuCl₃*3H₂O

Base Information

• Chemical Name: RuCl₃*3H₂O
• CAS No.: 16904-20-4
• Molecular Formula: Cl₃H₆O₃Ru
• Molecular Weight: 261.475
• Mol file: 16904-20-4.mol

Synonyms:

Chemical Property of RuCl₃*3H₂O

Chemical Property:

Purity/Quality:

Safty Information:

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• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of RuCl₃*3H₂O

There total 10 articles about RuCl₃*3H₂O which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 16.0%

potassium aquapentachlororuthenate(III) → {RuCl(H2O)5}(2+) (26167-23-7) + ruthenium(III)(H2O)3 chloride (15203-91-5,16904-21-5,13815-94-6,16904-20-4) + dichlorotetraaquoruthenium(III) (100349-08-4,99922-04-0,101314-06-1)

Guidance literature:

In hydrogenchloride; from a 10E-4M soln. of K2(RuCl5H2O) in 0.1M HCl after 74 d at 25°C;; eluation over Dowex-50W, one after another with H2O, 0.1M- and 1M HCl;;

DOI:10.1021/ja01477a014

Reference yield:

aquachlororuthenium(III) (31817-84-2) → {RuCl4(H2O)2}(1-) (44470-29-3,44470-28-2,100017-77-4) + ruthenium(III)(H2O)3 chloride (15203-91-5,16904-21-5,13815-94-6,16904-20-4) + {Ru(H2O)6}(4+) (434332-32-8)

Guidance literature:

In hydrogenchloride; agening process of a soln. of (RuCl5H2O)(2-) in 0.1 M HCl (freshly prepd. from K2RuCl5 and 0.1 M HCl) in a closed tube leads to (RuCl4(H2O)2)(1-),(RuCl3(H2O)3) and at least (Ru(H2O)6)(4+) at ambient temp.;; detn. by electrophoresis and absorption spectra after 0, 1, 3, 6, 10, 25, 45, 88 and 105 d; not isolated;;

Reference yield:

hydrogenchloride (7647-01-0,15364-23-5) + ruthenium(III)chloride (10049-08-8,63767-78-2) → RuCl3*3H2O (13815-94-6,15203-91-5,16904-20-4,16904-21-5) + RuCl3*3H2O (13815-94-6,15203-91-5,16904-20-4,16904-21-5)

Guidance literature:

In hydrogenchloride; 9.2 g commercially avaiable Ru-chloride in 50 ml 0.5 m HCl is refluxed over Hg for 24 h; the mer(trans)-compound is main product;; separation of the two isomeres by ionic exchange chromy. with H2O over Dowex-50 W and Dowex-1 at 0°C (UV-spect. determined); cryoscopic and gravimetric determination of the chemical compn.;;

DOI:10.1021/ja01501a018

upstream raw materials:

aquachlororuthenium(III)

hydrogenchloride

ruthenium(III)chloride

water

Downstream raw materials:

tris(triphenylphosphine)ruthenium(II) chloride

RuCl₃*3H₂O