Technology Process of C25H41O8P
There total 6 articles about C25H41O8P which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
Multi-step reaction with 2 steps
1: 4-toluenesulfonyl azide; sodium hydride / tetrahydrofuran; mineral oil / 3 h / 0 - 20 °C
2: rhodium (II) octanoate dimer / dichloromethane / 1 h / 85 °C / Inert atmosphere
With
4-toluenesulfonyl azide; rhodium (II) octanoate dimer; sodium hydride;
In
tetrahydrofuran; dichloromethane; mineral oil;
DOI:10.1021/ol3017676
- Guidance literature:
-
Multi-step reaction with 5 steps
1.1: sodium hydride / tetrahydrofuran; dimethyl sulfoxide; mineral oil / 1 h / 0 °C
1.2: 21 h / 0 - 20 °C
2.1: pyridine; sulfur trioxide pyridine complex; triethylamine / dichloromethane; dimethyl sulfoxide / 6 h / 0 - 20 °C
3.1: 1,8-diazabicyclo[5.4.0]undec-7-ene; lithium chloride / acetonitrile / 22 h / 0 - 20 °C
4.1: diisobutylaluminium hydride / tetrahydrofuran; dichloromethane / 1.5 h / -78 °C
5.1: rhodium (II) octanoate dimer / dichloromethane / 1 h / 85 °C / Inert atmosphere
With
pyridine; rhodium (II) octanoate dimer; sulfur trioxide pyridine complex; sodium hydride; diisobutylaluminium hydride; 1,8-diazabicyclo[5.4.0]undec-7-ene; triethylamine; lithium chloride;
In
tetrahydrofuran; dichloromethane; dimethyl sulfoxide; acetonitrile; mineral oil;
2.1: Parikh-Doering oxidation;
DOI:10.1021/ol3017676
- Guidance literature:
-
Multi-step reaction with 3 steps
1: 1,8-diazabicyclo[5.4.0]undec-7-ene; lithium chloride / acetonitrile / 22 h / 0 - 20 °C
2: diisobutylaluminium hydride / tetrahydrofuran; dichloromethane / 1.5 h / -78 °C
3: rhodium (II) octanoate dimer / dichloromethane / 1 h / 85 °C / Inert atmosphere
With
rhodium (II) octanoate dimer; diisobutylaluminium hydride; 1,8-diazabicyclo[5.4.0]undec-7-ene; lithium chloride;
In
tetrahydrofuran; dichloromethane; acetonitrile;
DOI:10.1021/ol3017676