3-methoxy-7α-iodomethyl-3-borabicyclo<3.3.1>nonane

Base Information

Chemical Name:3-methoxy-7α-iodomethyl-3-borabicyclo<3.3.1>nonane
CAS No.:128315-94-6
Molecular Formula:C₁₀H₁₈BIO
Molecular Weight:291.968
Hs Code.:

Synonyms:

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Chemical Property of 3-methoxy-7α-iodomethyl-3-borabicyclo<3.3.1>nonane

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Technology Process of 3-methoxy-7α-iodomethyl-3-borabicyclo<3.3.1>nonane

There total 1 articles about 3-methoxy-7α-iodomethyl-3-borabicyclo<3.3.1>nonane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 30.0%

: 61357-36-6
1-boraadamantane tetrahydrofuranate

: 865-34-9
lithium methanolate

: 74789-87-0
C₈H₁₃(CH₂OCH₃)B(OCH₃)

: dimethoxy[3,5-di(iodomethyl)cyclohex-1-ylmethyl]borane

: dimethoxy(3-iodomethyl-5-methoxymethylcyclohex-1-ylmethyl)borane

: 128315-94-6
3-methoxy-7α-iodomethyl-3-borabicyclo<3.3.1>nonane

Guidance literature:: With iodine; In tetrahydrofuran; methanol; under Ar, to ate complex (from THF complex in THF and MeOLi in MeOH) added dropwise at -30°C soln. of I2 in THF, heated to 20°C, cooled to -30°C, subsequently added MeOLi and I2 in THF, heated to 20°C; evapd., MeOH added, extd. with hexane, treated with Na2S2O3*5H2O, evapd., fractionally distd.; elem. anal.;
DOI:10.1016/S0022-328X(00)98647-9

Reference yield: 34.0%

: 19597-69-4,157302-05-1
lithium azide

: 128315-94-6
3-methoxy-7α-iodomethyl-3-borabicyclo<3.3.1>nonane

: 128315-96-8
7α-hydroxymethyl-3-azabicyclo<3.3.1>nonane

: 88269-11-8,136374-71-5
(3-Hydroxymethyl-5-methoxymethyl-cyclohexyl)-methanol

Guidance literature:: With sodium hydroxide; dihydrogen peroxide; In methanol; water; byproducts: N2; refluxing a mixt. of B-complex and LiN3 in MeOH (stirring, 15 h, dry Ar), concn. in vacuo, treating with NaOH in H2O, addn. of H2O2 (0°C), refluxing for 1 h; chromy. on silica gel;
DOI:10.1016/0022-328X(91)86035-O

Reference yield:

: 128315-94-6
3-methoxy-7α-iodomethyl-3-borabicyclo<3.3.1>nonane

: 281-27-6
1-aza-adamantane

Guidance literature:: Multi-step reaction with 2 steps

1: 1.) LiN₃, 2.) NaOH, 30percent H₂O₂ / 1.) reflux, 15 h, 2.) water, reflux, 1 h

2: 90 percent / SOCl₂ / benzene / 1.) 20 deg C, 0.5 h, 2.) reflux, 20 min

With sodium hydroxide; thionyl chloride; lithium azide; dihydrogen peroxide; In benzene;
DOI:10.1016/0022-328X(91)86035-O