74789-87-0

Basic information

• Product Name: C₈H₁₃(CH₂OCH₃)B(OCH₃)
• Synonyms: C₈H₁₃(CH₂OCH₃)B(OCH₃)
• CAS NO: 74789-87-0
• Molecular Weight: 196.098
• Mol File: 74789-87-0.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: C₈H₁₃(CH₂OCH₃)B(OCH₃)(CAS DataBase Reference)
• NIST Chemistry Reference: C₈H₁₃(CH₂OCH₃)B(OCH₃)(74789-87-0)
• EPA Substance Registry System: C₈H₁₃(CH₂OCH₃)B(OCH₃)(74789-87-0)

Safety Data

• Hazardous Substances Data: 74789-87-0(Hazardous Substances Data)

Upstream product

• 61357-36-6 1-boraadamantane tetrahydrofuranate 
• 865-34-9 lithium methanolate 
• 74789-86-9 3-methoxy-7-bromomethyl-3-borabicyclo[3.3.1]nonane 
• 124-41-4 sodium methylate 
• 109-89-7 diethylamine 

Relevant articles and documents

ORGANOBORON COMPOUNDS. CDIII. IODINATION OF ATE COMPLEXES OF 1-BORAADAMANTANE

The complex of 1-boraadamantane with tetrahydrofuran (1) reacts with iodine in the presence of lithium methylate or methyllithium to produce 3-methoxy- (III) and 3-methyl-7-iodomethyl-3-borabicyclononane (X), respectively.Further iodination of III in the presence of lithium methylate proceeds in a complicated manner due to replacement of iodine by the methoxy group in the starting compound.The high reactivity of the halogen in III permitted a one-pot synthesis of 3-methoxy-7-methoxymethyl-3-borabicyclononane from I.Iodination of lithium 1-isopropenyl-1-boraadamantanate leads, after methanolysis, to 3-methoxy-7-isobutenyl-3-borabicyclononane.The latter compound was converted to 7-isobutenyl-3-methyl-3-borabicyclononane on treatment with MeMgI.