di-p-tolylbismuth 4-methylbenzenesulfonate

Base Information

Chemical Name:di-p-tolylbismuth 4-methylbenzenesulfonate
CAS No.:108858-15-7
Molecular Formula:C₂₁H₂₁BiO₃S
Molecular Weight:562.442
Hs Code.:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of di-p-tolylbismuth 4-methylbenzenesulfonate

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Technology Process of di-p-tolylbismuth 4-methylbenzenesulfonate

There total 3 articles about di-p-tolylbismuth 4-methylbenzenesulfonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

: 171776-55-9
tri-p-tolylbismuth bis(4-methylbenzenesulfonate)

: 7732-18-5
water

: 603-36-1
triphenylantimony

: 108858-15-7
di-p-tolylbismuth 4-methylbenzenesulfonate

: μ-oxo-bis[(4-methylbenzenesulfonate)triphenylantimony]

Guidance literature:: In toluene; mixt. of tri-p-tolylbismuth bis(OSO2C6H4Me-4) and SbPh3 in toluene in presence of air moisture was kept in glass evacuated tube at 25°C for 72 h; crystals collected and dried; solvent removed from mother liquor and residue recrystd. from water;
DOI:10.1023/A:1022325831721

Reference yield: 80.0%

: 5142-75-6
tri(p-tolyl)bismuth

: 104-15-4
toluene-4-sulfonic acid

: 108858-15-7
di-p-tolylbismuth 4-methylbenzenesulfonate

Guidance literature:: In diethyl ether; mixing soln. of (CH3C6H4)3Bi in ether and soln. of toluenesulfonic acidin ether; stirring at room temp. for 15min; pptn., filtration; washing with ether; drying at room temp.; elem. anal.;
DOI:10.1016/S0020-1693(00)86855-3

Reference yield: 8.8%

: 7446-11-9
sulfur trioxide

: 5142-75-6
tri(p-tolyl)bismuth

: 108858-15-7
di-p-tolylbismuth 4-methylbenzenesulfonate

: 108858-19-1
BiO⁽¹⁺⁾*CH₃C₆H₄SO₃^(1-)=BiO(O₃SC₆H₄CH₃)

: (p-tolyl)bismuth ditosylate

Guidance literature:: In 1,2-dichloro-ethane; bubbling SO3 through soln. of (CH3C6H4)3Bi in 1,2-dichloroethane for 2hat -10°C; pptn. on addn. of ether, filtn.; extn. with dry ethanol (insol. residue: BiO(O3SC6H4CH3); evapn. to dryness, major product: (p-MeC6H4)2Bi(O3Sp-MeC6H4), minor product: (p-MeC6H4)Bi(O3Sp-MeC6H4)2; elem. anal.;
DOI:10.1016/S0020-1693(00)86855-3