copper(II) trans-meso-tetraphenyl-1-[3-(O-(3-methylene-2,2,5,5-tetramethylpirrolidinyl-1-oxy))acrylic ester]porphyrin

Base Information

• Chemical Name: copper(II) trans-meso-tetraphenyl-1-[3-(O-(3-methylene-2,2,5,5-tetramethylpirrolidinyl-1-oxy))acrylic ester]porphyrin
• CAS No.: 77629-60-8
• Molecular Formula: C₅₆H₄₆CuN₅O₃
• Molecular Weight: 900.559
• Mol file: 77629-60-8.mol

Synonyms:

Chemical Property of copper(II) trans-meso-tetraphenyl-1-[3-(O-(3-methylene-2,2,5,5-tetramethylpirrolidinyl-1-oxy))acrylic ester]porphyrin

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of copper(II) trans-meso-tetraphenyl-1-[3-(O-(3-methylene-2,2,5,5-tetramethylpirrolidinyl-1-oxy))acrylic ester]porphyrin

There total 5 articles about copper(II) trans-meso-tetraphenyl-1-[3-(O-(3-methylene-2,2,5,5-tetramethylpirrolidinyl-1-oxy))acrylic ester]porphyrin which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 49.0%

copper(II) trans-meso-tetraphenyl-1-(3-acrylic acid chloride)porphyrin (77629-56-2) + 3-hydroxymethyl-2,2,5,5-tetramethylpyrrolidinyl-1-oxy (27298-75-5) → copper(II) trans-meso-tetraphenyl-1-[3-(O-(3-methylene-2,2,5,5-tetramethylpirrolidinyl-1-oxy))acrylic ester]porphyrin (77629-60-8)

Guidance literature:

In tetrahydrofuran; pyridine; Pirrolidin in THF was added dropwise to a soln. of complex in THF-pyridine under N2, refluxed for 12 h;; evapd., ppt. was chromd. on silica gel in CHCl3 soln.; recrystd. from CHCl3-heptane; elem. anal.;;

Reference yield:

copper(II) trans-meso-tetraphenyl-1-(2-ethoxycarbonylvinyl)porphyrin (71774-36-2) → copper(II) trans-meso-tetraphenyl-1-[3-(O-(3-methylene-2,2,5,5-tetramethylpirrolidinyl-1-oxy))acrylic ester]porphyrin (77629-60-8)

Guidance literature:

Multi-step reaction with 3 steps

1: KOH / tetrahydrofuran; water; ethanol

2: benzene

3: tetrahydrofuran; pyridine

With KOH; In tetrahydrofuran; pyridine; ethanol; water; benzene;

Reference yield:

copper(II) cis-meso-tetraphenyl-1-(2-ethoxycarbonylvinyl)porphyrin (71763-50-3) → copper(II) cis-meso-tetraphenyl-1-[3-(O-(3-methylene-2,2,5,5-tetramethylpirrolidinyl-1-oxy))acrylic ester]porphyrin (77698-51-2) + copper(II) trans-meso-tetraphenyl-1-[3-(O-(3-methylene-2,2,5,5-tetramethylpirrolidinyl-1-oxy))acrylic ester]porphyrin (77629-60-8)

Guidance literature:

Multi-step reaction with 3 steps

1: KOH / tetrahydrofuran; water; ethanol

2: benzene

3: tetrahydrofuran; pyridine

With KOH; In tetrahydrofuran; pyridine; ethanol; water; benzene;

upstream raw materials:

copper(II) trans-meso-tetraphenyl-1-(3-acrylic acid chloride)porphyrin

3-hydroxymethyl-2,2,5,5-tetramethylpyrrolidinyl-1-oxy

copper(II) cis-meso-tetraphenyl-1-(3-acrylic acid)porphyrin

copper(II) trans-meso-tetraphenyl-1-(3-acrylic acid)porphyrin