MDT-14

Base Information

• Chemical Name: MDT-14
• CAS No.: 39646-84-9
• Molecular Formula: C₁₄H₂₀O₂
• Molecular Weight: 220.312
• Mol file: 39646-84-9.mol

Synonyms:

Chemical Property of MDT-14

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of MDT-14

There total 9 articles about MDT-14 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

4,9-dichlorodiamantane (32401-20-0) → MDT-14 (39646-84-9)

Guidance literature:

With water; sodium acetate; In N,N-dimethyl-formamide; at 150 ℃; for 21h; under 3000.3 Torr; Product distribution / selectivity;

Reference yield: 78.0%

diamantane (2292-79-7) → MDT-14 (39646-84-9)

Guidance literature:

diamantane; With nitric acid; Schlenk technique;

With sulfuric acid; Schlenk technique;

DOI:10.1002/adfm.201705786

Reference yield: 78.0%

diamantane (2292-79-7) → 4-hydroxydiamantane (30651-03-7) + MDT-14 (39646-84-9) + diamantan-1-ol (30545-19-8)

Guidance literature:

diamantane; With nitric acid; In dichloromethane; at 0 - 20 ℃; for 1h;

With sulfuric acid; In chloroform; at -15 - 0 ℃; for 1.5h; Further stages.;

DOI:10.1002/ejoc.200700378

upstream raw materials:

diamantane

4,9-dibromodiamantane

3-hydroxydiamantane

bicyclo[2.2.1]hepta-2,5-diene

Refernces

• 1、 Davis, Matthew C.,Liu, Shenggao. "Selective apical bromination of diamantane and conversion to the dihydroxy and dicarboxylic acid derivatives". . p. 3509 - 3514. Retrieved 2006.
• 2、 Zonker, Benjamin,Becker, Jonathan,Hrdina, Radim. "Synthesis of noradamantane derivatives by ring-contraction of the adamantane framework". . p. 4027 - 4031. Retrieved 2021/05/19.