1,1'-bis(mesitylthio)ferrocene

Base Information

• Chemical Name: 1,1'-bis(mesitylthio)ferrocene
• CAS No.: 305866-41-5
• Molecular Formula: C₂₈H₃₀FeS₂
• Molecular Weight: 486.525
• Mol file: 305866-41-5.mol

Synonyms:

Chemical Property of 1,1'-bis(mesitylthio)ferrocene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1,1'-bis(mesitylthio)ferrocene

There total 1 articles about 1,1'-bis(mesitylthio)ferrocene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

1,1'-dilithioferrocene (33272-09-2) + bis(2,4,6-trimethylphenyl)disulfide (1483-92-7) → 1,1'-bis(mesitylthio)ferrocene (305866-41-5)

Guidance literature:

In hexane; toluene; the soln. of disulfide in toluene was added to a soln. of Li-ferrocene in hexane, the mixt. was stirred for 16 h (N2); H2O was added, an aq. layer was extd. with CH2Cl2, dried over MgSO4, evapd., chromd. on alumina column (CH2Cl2-hexane), recrystd. by slow evapn. of a soln. of hot hexane; elem. anal.;

DOI:10.1021/om0004388

Reference yield: 40.0%

bis(benzonitrile)palladium(II) dichloride (15617-18-2,39958-10-6,14220-64-5) + 1,1'-bis(mesitylthio)ferrocene (305866-41-5) → Fe(C5H4SC6H2(CH3)3)2PdCl2 (305866-45-9)

Guidance literature:

In toluene; a mixt. in toluene was stirred at room temp. for 20 h (N2); the crystals were filtered, evapd. to dryness, washed with hot hexane, recrystd. from CH2Cl2-hexane; elem. anal.;

DOI:10.1021/om0004388

upstream raw materials:

1,1'-dilithioferrocene

bis(2,4,6-trimethylphenyl)disulfide

Downstream raw materials:

Fe(C₅H₄SC₆H₂(CH₃)3)2PdCl₂