1483-92-7Relevant articles and documents
Synthesis, Crystal Structure and Electronic Properties of a 2Fe-2S Complex with a Bulky Thiolato Ligand, 2
Ueyama, Norikazu,Ueno, Satoru,Sugawara, Takashi,Tatsumi, Kazuyuki,Nakamura, Akira,Yasuoka, Noritake
, p. 2723 - 2728 (1991)
The complex 2 (tmbt = 2,4,6-trimethylbenzenethiolate) was synthesised and its molecular structure determined.The crystal system is monoclinic with a = 15.241(6), b = 16.174(5), c = 16.768(6) Angstroem, β = 135.84(2) deg and Z = 2, in s
A facile synthesis of bisulfides by oxidation of thiols with bis(trichloromethyl) carbonate and triphenylphosphine oxide
Li,Liang,Su
, p. 613 - 616 (2003)
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Synthesis and crystal structure of an arenesulfenyl iodide with unprecedented stability
Goto, Kei,Holler, Michel,Okazaki, Renji
, p. 1915 - 1916 (1998)
An arenesulfenyl iodide with unprecedented stability was synthesized by oxidation of a thiol bearing a novel bowl-type substituent with iodine, whose monomeric structure was determined by X-ray crystallographic analysis.
Transformation of arylboronic acids with sodium thiosulfate into organodisulfides catalyzed by a recyclable polyoxometalate-based Cr(iii) catalyst
Chang, Yalin,Li, Huiyi,Tao, Chaofu,Wang, Aiping,Wei, Yongge,Xie, Ya,Yu, Han,Yu, Shunming
supporting information, p. 6059 - 6064 (2021/08/23)
Organo disulfides represent an abundant class of compounds in chemical biology, pharmaceutical fields, and industry. They are traditionally synthesized by the oxidation of mercaptan in the presence of an organic ligand supported metal catalyst or toxic oxidants under harsh conditions. Here, we disclose a highly-efficient pathway in which disulfide is synthesized by organic boric acid and Na2S2O3 using the catalyst (NH4)3[CrMo6O18(OH)6], demonstrating a high activity and excellent selectivity. Various boric acid derivatives have been successfully transformed into the corresponding disulfides. Mechanistic insights have been furnished based on the observation of intermediate and control experiments.