(1S)-1-(2-methylphenyl)ethan-1-ol

Base Information

Chemical Name:(1S)-1-(2-methylphenyl)ethan-1-ol
CAS No.:51100-05-1
Molecular Formula:C₉H₁₂O
Molecular Weight:136.194
Hs Code.:
European Community (EC) Number:839-732-8
Nikkaji Number:J63.399B
Mol file:51100-05-1.mol

Synonyms:(1S)-1-(2-methylphenyl)ethan-1-ol;51100-05-1;(1S)-1-(2-METHYLPHENYL)ETHANOL;(S)-1-(2-Methylphenyl)ethyl alcohol;(S)-1-(o-Tolyl)ethanol;(s)-1-(2-methylphenyl)ethanol;SCHEMBL3073519;(s)-1-(o-methylphenyl)ethanol;MFCD09863725;CS-0250891;EN300-52638;E84419

Suppliers and Price of (1S)-1-(2-methylphenyl)ethan-1-ol

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
(1S)?-?1-?(2-?Methylphenyl)?ethanol
250mg
$ 440.00

American Custom Chemicals Corporation
(1S)-1-(2-METHYLPHENYL)ETHAN-1-OL 95.00%
5G
$ 1928.08

American Custom Chemicals Corporation
(1S)-1-(2-METHYLPHENYL)ETHAN-1-OL 95.00%
2.5G
$ 1473.14

American Custom Chemicals Corporation
(1S)-1-(2-METHYLPHENYL)ETHAN-1-OL 95.00%
1G
$ 620.55

AK Scientific
(1S)-1-(2-Methylphenyl)ethanol
100mg
$ 349.00

Total 11 raw suppliers

Chemical Property of (1S)-1-(2-methylphenyl)ethan-1-ol

Chemical Property:

Boiling Point:216℃
PKA:14.44±0.20(Predicted)
Flash Point:104℃
Density:0.995
XLogP3:1.8
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:1
Exact Mass:136.088815002
Heavy Atom Count:10
Complexity:101

Purity/Quality:

98%Min ^*data from raw suppliers

(1S)?-?1-?(2-?Methylphenyl)?ethanol ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:CC1=CC=CC=C1C(C)O
Isomeric SMILES:CC1=CC=CC=C1[C@H](C)O
Uses (1S)?-?1-?(2-?Methylphenyl)?ethanol is a bulding block used in pharmaceutical synthesis and are racemized by pincer-type catalysts.

Technology Process of (1S)-1-(2-methylphenyl)ethan-1-ol

There total 55 articles about (1S)-1-(2-methylphenyl)ethan-1-ol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: 75-24-1
trimethylaluminum

: 529-20-4
2-methylphenyl aldehyde

: 7287-82-3,42070-90-6,51100-05-1,99531-03-0
(S)-1-(2-Methylphenyl)ethanol

: 42070-90-6
(R)-1-(2-methylphenyl)ethanol

Guidance literature:: trimethylaluminum; 2-methylphenyl aldehyde; With titanium(IV) isopropylate; (S_a)-2'-[(R)-hydroxy(phenyl)methyl]-(1,1'-binaphthalen)-2-ol; In diethyl ether; toluene; at 0 ℃; for 1h; Inert atmosphere;

With hydrogenchloride; In diethyl ether; water; toluene; optical yield given as %ee; enantioselective reaction; Inert atmosphere;
DOI:10.1016/j.tetasy.2012.05.007

Reference yield: 50.0%

: 7287-82-3
1-O-tolyl-ethanol

: 7287-82-3,42070-90-6,51100-05-1,99531-03-0
(S)-1-(2-Methylphenyl)ethanol

: 42070-90-6
(R)-1-(2-methylphenyl)ethanol

: 577-16-2,122382-54-1
2-Methylacetophenone

Guidance literature:: With (1R)-N-oxyl-1-(N-benzylcarbamoyl)-8-azabicyclo[3.2.1]octane; sodium hydrogencarbonate; sodium bromide; In dichloromethane; water; at 0 ℃; optical yield given as %ee; enantioselective reaction; Electrochemical reaction;
DOI:10.1016/j.tetasy.2008.12.011

Reference yield: 48.0%

: 7287-82-3
1-O-tolyl-ethanol

: 7287-82-3,42070-90-6,51100-05-1,99531-03-0
(S)-1-(2-Methylphenyl)ethanol

Guidance literature:: With C₄₆H₃₄I₄O₆; 1,1,1,3,3,3-hexamethyl-disilazane; In dichloromethane; at -30 ℃; for 2h; Reagent/catalyst; stereoselective reaction;