C₆H₃(CH₂PC₆H₅C(CH₃)3)2PdBr

Base Information

• Chemical Name: C₆H₃(CH₂PC₆H₅C(CH₃)3)2PdBr
• CAS No.: 404849-92-9
• Molecular Formula: C₂₈H₃₅BrP₂Pd
• Molecular Weight: 619.857
• Mol file: 404849-92-9.mol

Synonyms:

Chemical Property of C₆H₃(CH₂PC₆H₅C(CH₃)3)2PdBr

Chemical Property:

Purity/Quality:

Safty Information:

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Technology Process of C₆H₃(CH₂PC₆H₅C(CH₃)3)2PdBr

There total 1 articles about C₆H₃(CH₂PC₆H₅C(CH₃)3)2PdBr which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 19.0%

tris(dibenzylideneacetone)dipalladium(0) chloroform complex (52522-40-4) + 1,3-{bis[(tert-butyl)(phenyl)phosphino]methyl}benzene (404849-82-7) → C6H3(CH2PC6H5C(CH3)3)2PdBr (404849-92-9)

Guidance literature:

In benzene; (N2); reacting diphosphine with palladium complex in benzene for 12 h; filtration through SiO2 in ether, column chromy (SiO2, CH2Cl2), crystn. (acetone/hexane, -30°C), washing with hexane; elem. anal.;

DOI:10.1002/1522-2675(20011114)84:11<3519::AID-HLCA3519>3.0.CO;2-9

Reference yield: 95.0%

C6H3(CH2PC6H5C(CH3)3)2PdBr (404849-92-9) + water (7732-18-5) + silver trifluoromethanesulfonate (2923-28-6) + acetone (67-64-1) → [C6H3(CH2PC6H5C(CH3)3)2PdOH2](1+)*OSO2CF3(1-)*CH3COCH3=[C6H3(CH2PC6H5C(CH3)3)2PdOH2]OSO2CF3*CH3COCH3

Guidance literature:

In water; acetone; (N2); addn. of silver salt to a soln. of palladium complex in wet acetone, stirring for 1 h; filtration through Celite, addn. of hexane; elem. anal.;

DOI:10.1002/1522-2675(20011114)84:11<3519::AID-HLCA3519>3.0.CO;2-9

upstream raw materials:

tris(dibenzylideneacetone)dipalladium⁽⁰⁾ chloroform complex

1,3-{bis[(tert-butyl)(phenyl)phosphino]methyl}benzene