[cis-mer-Ru(triflato)(CO)(⁽¹³⁾CO-trans to P(C))(PhP(CH₂CH₂CH₂PCy₂)2)](triflate)

Base Information

Chemical Name:[cis-mer-Ru(triflato)(CO)(⁽¹³⁾CO-trans to P(C))(PhP(CH₂CH₂CH₂PCy₂)2)](triflate)
CAS No.:851369-73-8
Molecular Formula:CF₃O₃S*C₃₉H₆₁F₃O₅P₃RuS
Molecular Weight:1043.02
Hs Code.:

[cis-mer-Ru(triflato)(CO)(<sup>(13)</sup>CO-trans to P(C))(PhP(CH<sub>2</sub>CH<sub>2</sub>CH<sub>2</sub>PCy<sub>2</sub>)2)](triflate)

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Chemical Property of [cis-mer-Ru(triflato)(CO)(⁽¹³⁾CO-trans to P(C))(PhP(CH₂CH₂CH₂PCy₂)2)](triflate)

Chemical Property:

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Technology Process of [cis-mer-Ru(triflato)(CO)(⁽¹³⁾CO-trans to P(C))(PhP(CH₂CH₂CH₂PCy₂)2)](triflate)

There total 2 articles about [cis-mer-Ru(triflato)(CO)(⁽¹³⁾CO-trans to P(C))(PhP(CH₂CH₂CH₂PCy₂)2)](triflate) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 141686-25-1
cis-mer-Ru(triflato)2(CO)(PhP(CH₂CH₂CH₂PCy₂)2)

: 1641-69-6
[13C]Carbon monoxide

: 851369-73-8,851515-88-3
[cis-mer-Ru(triflato)(CO)(⁽¹³⁾CO-trans to P(C))(PhP(CH₂CH₂CH₂PCy₂)2)](triflate)

Guidance literature:: In methanol; under Ar; soln. of Ru complex in MeOH evacuated; (13)CO gas introduced; flask closed; stirred for 15 min; pressure returned to 1 atm by introduction of additional (13)CO; repeated; monitored by (31)P NMR spectra;
DOI:10.1016/j.ica.2004.11.049

Reference yield:

: 851369-77-2
cis-mer-Ru(triflato)2(⁽¹³⁾CO)(PhP(CH₂CH₂CH₂PCy₂)2)

: 201230-82-2
carbon monoxide

: 851369-73-8,851515-88-3
[cis-mer-Ru(triflato)(CO)(⁽¹³⁾CO-cis to all P)(PhP(CH₂CH₂CH₂PCy₂)2)](triflate)

Guidance literature:: In acetone; CO passed through stirred soln. of Ru complex in acetone at room temp. for 15 min; detd. by (13)C and (31)P NMR spectra;
DOI:10.1016/j.ica.2004.11.049

Reference yield:

: 851369-73-8,851515-88-3
[cis-mer-Ru(triflato)(CO)(⁽¹³⁾CO-trans to P(C))(PhP(CH₂CH₂CH₂PCy₂)2)](triflate)

: 201230-82-2
carbon monoxide

: 83146-93-4
mer-Ru(CO)2(PhP(CH₂CH₂CH₂PCy₂)2)

: 851369-76-1,851515-89-4
mer-Ru(CO)(⁽¹³⁾CO)(PhP(CH₂CH₂CH₂PCy₂)2)

Guidance literature:: With n-butyllithium; In tetrahydrofuran; Ru complex reacted with n-BuLi (>2 equiv.) in THF under CO atmosphere; detd. by (13)C and (31)P NMR spectra; mixt. of three Ru complexes (unlabeled and syn and anti isomers of (13)CO-Ru complex) obtained;
DOI:10.1016/j.ica.2004.11.049