BIS(TRIFLUOROMETHYL)NITROXIDE

Base Information

• Chemical Name: BIS(TRIFLUOROMETHYL)NITROXIDE
• CAS No.: 2154-71-4
• Molecular Formula: C2F6 N O
• Molecular Weight: 168.019
• Mol file: 2154-71-4.mol

Synonyms:Bis(trifluoromethyl)nitroxide; Bis(trifluoromethyl) nitroxide radical;Bis(trifluoromethyl)aminooxyl; Bis(trifluoromethyl)nitroxyl;N,N-Bis(trifluoromethyl)aminooxyl

Chemical Property of BIS(TRIFLUOROMETHYL)NITROXIDE

Chemical Property:

• Melting Point: -69.9°C
• Boiling Point: -25°C
• PSA: 3.24000
• LogP: 1.67350

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Statements: 23/24/25
• Safety Statements: 23-36/37/39-38

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of BIS(TRIFLUOROMETHYL)NITROXIDE

There total 6 articles about BIS(TRIFLUOROMETHYL)NITROXIDE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

bis(trifluoroacetyl)peroxide (383-73-3) + C6H10NO4(1-)*Na(1+) → levulinic acid methyl ester (624-45-3) + bis-trifluoromethyl-aminooxyl (2154-71-4) + sodium 2,2,2-trifluoroacetate (2923-18-4) + C7H10F3N2O5

Guidance literature:

In 1,1,2-Trichloro-1,2,2-trifluoroethane; at 20 ℃;

DOI:10.1021/ja00271a068

Reference yield:

bis(trifluoroacetyl)peroxide (383-73-3) → trifluoronitrosomethane (334-99-6) + bis-trifluoromethyl-aminooxyl (2154-71-4)

Guidance literature:

With sodium nitrite; In 1,1,2-Trichloro-1,2,2-trifluoroethane; at 20 ℃;

DOI:10.1016/S0022-1139(00)81074-X

Reference yield:

bis(trifluoroacetyl)peroxide (383-73-3) → bis-trifluoromethyl-aminooxyl (2154-71-4) + sodium 2,2,2-trifluoroacetate (2923-18-4) + C4H6F3N2O3

Guidance literature:

With lithium 2-nitropropane; In 1,1,2-Trichloro-1,2,2-trifluoroethane; at 20 ℃;

DOI:10.1021/ja00271a068

upstream raw materials:

bis(trifluoroacetyl)peroxide

sodium 2-nitropropane

tris(pentafluorophenyl)-bis{bis(trifluoromethyl)aminooxy}stiborane

Downstream raw materials:

Perfluor-<1,2-bis-(N,N-dimethylnitroxy)-propan

N,N-Bis(trifluoromethyl)amine

N,N-bis(trifluoromethyl)hydroxylamine

Perfluoro-2-azapropen

Refernces

• 1、 Zhao, Cheng-Xue,Jiang, Xi-Kui,Chen, Guo-Fei,Qu, Yan-Ling,Wang, Xian-Shan,Lu, Jian-Ying. "Novel Technique for the Generation of Bis(polyfluoroalkyl) and Polyfluoroalkyl Nitroalkyl Nitroxides. ESR Verification of Mechanistic Propositions for the Reactions between Polyfluorodiacyl Peroxides and Carbanions Derived from Secondary Nitroalkanes". . p. 3132 - 3133. Retrieved 2007/10/02.