trans-RuCl2(κ4-N,N'-bis[o-(dipenylphosphino)benzylidene]-1,2-diiminoethane)

Base Information

• Chemical Name: trans-RuCl2(κ4-N,N'-bis[o-(dipenylphosphino)benzylidene]-1,2-diiminoethane)
• CAS No.: 189310-92-7
• Molecular Formula: C₄₀H₃₄Cl₂N₂P₂Ru
• Molecular Weight: 776.647
• Mol file: 189310-92-7.mol

Synonyms:

Chemical Property of trans-RuCl2(κ4-N,N'-bis[o-(dipenylphosphino)benzylidene]-1,2-diiminoethane)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of trans-RuCl2(κ4-N,N'-bis[o-(dipenylphosphino)benzylidene]-1,2-diiminoethane)

There total 2 articles about trans-RuCl2(κ4-N,N'-bis[o-(dipenylphosphino)benzylidene]-1,2-diiminoethane) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 35.0%

trans-RuCl2(κ4-N,N'-bis[o-(dipenylphosphino)benzylidene]-1,2-diaminoethane) (172703-18-3,175520-87-3) + chloroform (67-66-3,8013-54-5) + water (7732-18-5) → trans-RuCl2(κ4-N,N'-bis[o-(dipenylphosphino)benzylidene]-1,2-diiminoethane) (189310-92-7) + trans-RuCl2(κ4-L(5))*0.5CHCl3*2H2O

Guidance literature:

With H₂O₂; In ethanol; chloroform; under N2 or in vac.; to a soln. of Ru-contg. compd. (0.230 mmol) in CHCl3-EtOH mixt. an excess of H2O2 (0.617 mmol) was added; stirring at room temp. for 20 h; the solvent was removed; the soln. of the solid in acetone was chromd. on a silica gel column; a deep blue band were obtained when eluting with ethyl acetate; removal of the solvent from the blue band; the blue solid was recrystd. from a chloroform-hexane mixt.; elem. anal.; (31)P NMR spectra monitoring;

DOI:10.1039/b106997g

Reference yield:

dichlorotris(triphenylphosphine)ruthenium(II) (15529-49-4,41756-81-4) + N,N′-bis[o-(diphenylphosphino)benzylidene]ethylenediimine → trans-RuCl2(κ4-N,N'-bis[o-(dipenylphosphino)benzylidene]-1,2-diiminoethane) (189310-92-7)

Guidance literature:

In dichloromethane; Ru-contg. compd. reacted at room temp. in CH2Cl2 soln. with 1 equiv. of a ligand; according to J.-X. Gao et al. Polyhedron, 1996, 16, 1241;

DOI:10.1039/b106997g

upstream raw materials:

dichlorotris(triphenylphosphine)ruthenium(II)

trans-RuCl2(κ4-N,N'-bis[o-(dipenylphosphino)benzylidene]-1,2-diaminoethane)

chloroform

water