cis[(CH₃)(C₆H₅)2P]PdCl₂

Base Information

• Chemical Name: cis[(CH₃)(C₆H₅)2P]PdCl₂
• CAS No.: 26973-01-3
• Molecular Formula: C₂₆H₂₆Cl₂P₂Pd
• Molecular Weight: 577.766
• Mol file: 26973-01-3.mol

Synonyms:

Chemical Property of cis[(CH₃)(C₆H₅)2P]PdCl₂

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of cis[(CH₃)(C₆H₅)2P]PdCl₂

There total 12 articles about cis[(CH₃)(C₆H₅)2P]PdCl₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 48.0%

cis-{PdMe2(PMePh2)2} → PdCl2(PMePh2)2 (29484-75-1,26973-01-3,52611-08-2)

Guidance literature:

With trichlorosilane; In diethyl ether; byproducts: HSiCl2CH3; (N2), dried solvents, ice cooling, stirring 2h; evapn., added petroleum ether, (MePh2P)2PdCl2 ppt., filtration, washed (petroleum ether, 3 times), dried (high vac.), elem. anal., (1)H-NMR, (31)P-NMR;

DOI:10.1016/0022-328X(89)85042-9

Reference yield: 15.0%

tetrakis(methyldiphenylphosphine)palladium (24981-80-4) + diphenylantimony(III) chloride (2629-47-2) → PdCl2(PMePh2)2 (29484-75-1,26973-01-3,52611-08-2) + Sb4[tetrakis(diphenylmethylphosphine)palladium] dichlorodiphenylantimonide

Guidance literature:

In tetrahydrofuran; byproducts: PPh2Me, PhPh; inert atmosphere; stirring (room temp., 15 h, pptn.); vol. reduction, filtration, repeated washing (ether), drying (vac.); elem. anal.;

DOI:10.1021/ja982902u

Reference yield:

(P(C6H5)2CH3)2Pd(CH2SCH3)Cl → PdCl2(PMePh2)2 (29484-75-1,26973-01-3,52611-08-2)

Guidance literature:

With hydrogenchloride; In chloroform-d1; bubbling of HCl through soln.; pptn.; elem. anal.;

DOI:10.1016/S0020-1693(00)88731-9

upstream raw materials:

diphenyl(methyl)phosphine

tetrakis(methyldiphenylphosphine)palladium

diphenylantimony(III) chloride

potassium tetrachloropalladate(II)

Downstream raw materials:

[Pd(N₃)2(P(C₆H₅)2CH₃)2]

[(CH₃)(C₆H₅)2P]2PdBr₂

trans-PdBr₂(PMePh₂)2

{2,2-(MePPh₂)2-closo-2,1-PdTeB₁₀H₁₀}