Technology Process of ((C6H5)3PAu)3Mn(CO)4
There total 4 articles about ((C6H5)3PAu)3Mn(CO)4 which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
In
tetrahydrofuran;
Irradiation (UV/VIS); dissolving Ph3PAuMn(CO)5 (0.38 mmol), Ph3PAuNCO (0.38 mmol) and Ph3PAuN3 (0.12 mmmol) in freshly distd. THF; irradiation for 30 min with high-pressure-Hg-lamp;; evapn. to dryness; taking up residue in CH2Cl2, filtering; column chromy. (Al2O3, THF); elem. anal.;;
- Guidance literature:
-
With
KB[CH(CH3)C2H5]3H;
In
tetrahydrofuran;
Soln. of K compd. added to soln. of carbonyl compd. with stirring, after 30 min mixt. added to suspn. of Au complex in THF, stirred for 2 h at room temp.; filtered, n-hexane added to filtrate, allowed to stand in refrigerator for 1 d, filtered, washed with n-hexane, dried in vac., washed with toluene, dissolved in THF, n-hexane layered, crystd. at room temp in dark;
DOI:10.1515/znb-2000-1004
- Guidance literature:
-
With
KB[CH(CH3)C2H5]3H;
In
tetrahydrofuran;
Soln. of K compd. added to soln. of carbonyl compd. with stirring, after 30 min mixt. added to suspn. of Au complex in THF, stirred for 2 h at room temp.; filtered, n-hexane added to filtrate, allowed to stand in refrigerator for 1 d, filtered, washed with n-hexane, dried in vac.;
DOI:10.1515/znb-2000-1004
