{3-(p-toluenesulphinyl)propyl}triphenyltin

Base Information

• Chemical Name: {3-(p-toluenesulphinyl)propyl}triphenyltin
• CAS No.: 77329-31-8
• Molecular Formula: C₂₈H₂₈OSSn
• Molecular Weight: 531.306
• Mol file: 77329-31-8.mol

Synonyms:

Chemical Property of {3-(p-toluenesulphinyl)propyl}triphenyltin

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of {3-(p-toluenesulphinyl)propyl}triphenyltin

There total 1 articles about {3-(p-toluenesulphinyl)propyl}triphenyltin which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

{3-(p-tolylthio)propyl}triphenyltin (77329-29-4) + 3-chloro-benzenecarboperoxoic acid (937-14-4) → {3-(p-toluenesulphinyl)propyl}triphenyltin (77329-31-8)

Guidance literature:

In dichloromethane; m-chloroperbenzoic acid CH2Cl2 solution (1 eq.) dropwise addition to tin compound CH2Cl2 solution, stirring overnight; washing twice with 5% NaHCO3 soln., drying of org. layer with MgSO4, filtration, evapn., recrystn. (methanol), elem. anal.;

DOI:10.1016/S0022-328X(00)98614-5

Reference yield: 63.0%

{3-(p-toluenesulphinyl)propyl}triphenyltin (77329-31-8) + mercury dichloride → {3-(p-toluenesulphinyl)propyl}diphenyltin chloride (86012-03-5)

Guidance literature:

In ethanol; byproducts: C6H5HgCl; stirring of ethanol solution of starting compounds at 50°C for 3 h; cooling, filtration, evapn., crystn. (CHCl3/petroleum ether), elem. anal.;

DOI:10.1016/S0022-328X(00)98614-5

Reference yield:

{3-(p-toluenesulphinyl)propyl}triphenyltin (77329-31-8) → (C6H5)2ISnCH2CH2CH2S(O)C6H4CH3

Guidance literature:

With I₂; In tetrachloromethane; byproducts: C6H5I; dropwise addition of dilute iodine solution in CCl4 to CCl4 solution of tin compound at 25°C;

DOI:10.1016/S0022-328X(00)98614-5

upstream raw materials:

{3-(p-tolylthio)propyl}triphenyltin

3-chloro-benzenecarboperoxoic acid

Downstream raw materials:

{3-(p-toluenesulphinyl)propyl}diphenyltin chloride

{3-(p-toluenesulphinyl)propyl}diphenyltin chloride