[PdBr₂(PEt₃)2]

Base Information

Chemical Name:[PdBr₂(PEt₃)2]
CAS No.:15638-55-8
Molecular Formula:C₁₂H₃₀Br₂P₂Pd
Molecular Weight:502.546
Hs Code.:

Synonyms:

Suppliers and Price of [PdBr₂(PEt₃)2]

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of [PdBr₂(PEt₃)2]

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of [PdBr₂(PEt₃)2]

There total 3 articles about [PdBr₂(PEt₃)2] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

: 52230-29-2
tetrakis(triethylphosphine)palladium

: 862672-29-5
trans-NC₅H₄CHCHC₆F₄Br

: 15638-55-8,30184-36-2
[PdBr₂(PEt₃)2]

: [PdBr(C₆F₄CHCHC₅H₄N)(PEt₃)2]

Guidance literature:: In tetrahydrofuran; byproducts: P(CH2CH3)3, NC5H4CHCHC6F4H; reaction of palladium compd. with aryl bromide in dry THF at room temp. for 5 min; NMR;
DOI:10.1021/om200898t

Reference yield: 61.0%

: {(t-BuSCH2(t-Bu))PhPd(μMeCO2)2Pd(μMeCO2)2PdPh(t-BuSCH2(t-Bu))}

: 15638-55-8,30184-36-2
trans-dibromobis(triethylphosphine)palladium(II)

: trans-{PdBr(Ph)(PEt₃)2}

Guidance literature:: With lithium bromide; In acetone; an acetone soln. of diphenyltripalladium(II) complex and PEt3 was stirred at room temp., then LiBr was added;
DOI:10.1039/c39870000941

Reference yield: 61.0%

: {(t-BuSCH2(t-Bu))PhPd(μMeCO2)2Pd(μMeCO2)2PdPh(t-BuSCH2(t-Bu))}

: 7550-35-8
lithium bromide

: 554-70-1
triethylphosphine

: 15638-55-8,30184-36-2
trans-dibromobis(triethylphosphine)palladium(II)

: trans-{PdBr(Ph)(PEt₃)2}

Guidance literature:: In acetone; Et3P was added to a solution of the Pd-complex in acetone; stirred at room temperature for 4h; adding of LiBr/water; further stirring for 20h; evaporated to dryness; residue chromatographed ona silica column(200mesh,1.8*16cm); yellow fraction eluted with benzene; collected; evaporated to dryness; another yellow fraction was eluted by CH2Cl2/Et2O(3/1);
DOI:10.1246/bcsj.62.1081