[(C₂H₄(P(C₆H₅)2)2)Pd(CH₃CHCHCHC₆H₅)]⁽¹⁺⁾*BF₄^(1-)=[(C₂H₄(P(C₆H₅)2)2)Pd(CH₃CHCHCHC₆H₅)]BF₄

Base Information

• Chemical Name: [(C₂H₄(P(C₆H₅)2)2)Pd(CH₃CHCHCHC₆H₅)]⁽¹⁺⁾*BF₄^(1-)=[(C₂H₄(P(C₆H₅)2)2)Pd(CH₃CHCHCHC₆H₅)]BF₄
• CAS No.: 657403-39-9
• Molecular Formula: BF₄*C₃₆H₃₅P₂Pd
• Molecular Weight: 722.846
• Mol file: 657403-39-9.mol

Synonyms:

Chemical Property of [(C₂H₄(P(C₆H₅)2)2)Pd(CH₃CHCHCHC₆H₅)]⁽¹⁺⁾*BF₄^(1-)=[(C₂H₄(P(C₆H₅)2)2)Pd(CH₃CHCHCHC₆H₅)]BF₄

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [(C₂H₄(P(C₆H₅)2)2)Pd(CH₃CHCHCHC₆H₅)]⁽¹⁺⁾*BF₄^(1-)=[(C₂H₄(P(C₆H₅)2)2)Pd(CH₃CHCHCHC₆H₅)]BF₄

There total 3 articles about [(C₂H₄(P(C₆H₅)2)2)Pd(CH₃CHCHCHC₆H₅)]⁽¹⁺⁾*BF₄^(1-)=[(C₂H₄(P(C₆H₅)2)2)Pd(CH₃CHCHCHC₆H₅)]BF₄ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

sodium tetrafluoroborate (13755-29-8) + (-)-(1S,2R,3R)-di-μ-chloro-bis(1-methyl-3-phenyl-π-allyl)dipalladium (88155-41-3,88076-44-2,165876-46-0) + 1,2-bis-(diphenylphosphino)ethane (1663-45-2) → [Pd(eta.3-CH3CHCHCHPh)(1,2-bis(diphenylphosphino)ethane)][BF4] (657403-39-9,88083-20-9,869639-54-3)

Guidance literature:

In chloroform; react. (-)-(1S,2R,3R)-di-μ-chloro-bis(1-methyl-3-phenyl-π-allyl)dipalladium with 1,2-bis(diphenylphosphino)ethane and sodium tetrafluoroborate in chloroform;

DOI:10.1039/c39840000107

Reference yield: 45.7%

silver tetrafluoroborate (14104-20-2) + (-)-(1S,2R,3R)-di-μ-chloro-bis(1-methyl-3-phenyl-π-allyl)dipalladium (88155-41-3,88076-44-2,165876-46-0) + 1,2-bis-(diphenylphosphino)ethane (1663-45-2) → [Pd(eta.3-CH3CHCHCHPh)(1,2-bis(diphenylphosphino)ethane)][BF4] (657403-39-9,88083-20-9,869639-54-3)

Guidance literature:

In dichloromethane; acetone; byproducts: AgCl; mixt. of Ag salt (2 equiv.) and Pd complex (1 equiv.) placed under vac. and purged with N2; acetone added; mixt. stirred under N2 for 1 h; filtered through Celite; soln. of P ligand (2 equiv.) in CH2Cl2 added to filtrate under N2; soln. stirred for 1 h; filtered through Celite; rinsed with CH2Cl2; evapd. under vac.; elem. anal.;

DOI:10.1021/om0505514

Reference yield: 44.0%

sodium tetrafluoroborate (13755-29-8) + (1,2-bis(diphenylphosphanyl)ethane)dichloridopalladium(II) (19978-61-1) + (E)‐4‐phenylbut‐3‐en‐2‐yl acetate (74457-38-8,82045-04-3,84519-63-1,86668-34-0,97996-33-3,100017-26-3,104974-61-0,135758-86-0,145167-20-0,88154-75-0) → [(C2H4(P(C6H5)2)2)Pd(CH3CHCHCHC6H5)](1+)*BF4(1-)=[(C2H4(P(C6H5)2)2)Pd(CH3CHCHCHC6H5)]BF4 (88083-20-9,657403-39-9,869639-54-3)

Guidance literature:

With diisobutylaluminium hydride; triphenylphosphine; In diethyl ether; mixt. of complex and 1 equiv of PPh3 treated with 2 equiv of diisobutylaluminium hydride ,excess of (S)-(E)-3-acetoxy-1-phenyl-1-butene added, stirred at room temp. for 12 h, NaBF4 added; extd. (CHCl3), chromd. (SiO2, TLC, hexane/EtOAc); elem. anal.;

DOI:10.1021/ja00364a062

upstream raw materials:

sodium tetrafluoroborate

(-)-(1S,2R,3R)-di-μ-chloro-bis(1-methyl-3-phenyl-π-allyl)dipalladium

1,2-bis-(diphenylphosphino)ethane

silver tetrafluoroborate