(trans-PP, cis-HH)[RuH₂(PPh₃)2(ethylenediamine)]

Base Information

Chemical Name:(trans-P***P, cis-H***H)[RuH₂(PPh₃)2(ethylenediamine)]
CAS No.:229948-81-6
Molecular Formula:C₃₈H₄₀N₂P₂Ru
Molecular Weight:687.767
Hs Code.:

(trans-P***P, cis-H***H)[RuH<sub>2</sub>(PPh<sub>3</sub>)2(ethylenediamine)]

Synonyms:

Suppliers and Price of (trans-P***P, cis-H***H)[RuH₂(PPh₃)2(ethylenediamine)]

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of (trans-P***P, cis-H***H)[RuH₂(PPh₃)2(ethylenediamine)]

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of (trans-P***P, cis-H***H)[RuH₂(PPh₃)2(ethylenediamine)]

There total 4 articles about (trans-P***P, cis-H***H)[RuH₂(PPh₃)2(ethylenediamine)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 45.0%

: 60879-62-1
(trans-H***Cl, cis-P***P)[RuHCl(PPh₃)2(ethylenediamine)]

: 1333-74-0
hydrogen

: 229948-81-6,229962-76-9,494869-17-9
[RuH₂(PPh₃)2(ethylenediamine)]

Guidance literature:: With potassium n-butoxide; In tetrahydrofuran; byproducts: KCl, C4H9OH; using Schlenk, vac. line, glove box techniques in dry, O2 - free solvents; Ru complex and KO(t-Bu) were mixed under N2 atm.; THF added; mixt. stirred for 1 min; filtered; H2 bubbled for 2 min while being stirred; hexane added; stirred for 30 min; ppt. filtered; dried (vac.);
DOI:10.1021/ja039396f

Reference yield: 32.0%

: 60879-62-1
(trans-H***Cl, cis-P***P)[RuHCl(PPh₃)2(ethylenediamine)]

: 229948-81-6,229962-76-9,494869-17-9
(trans-P***P, cis-H***H)[RuH₂(PPh₃)2(ethylenediamine)]

: (cis-H***H, cis-P***P)[RuH₂(PPh₃)2(ethylenediamine)]

: [Ru2H2(PPh3)2(μ-eta.-2,η4-1,4-diazabutadiene)]

Guidance literature:: With potassium n-butoxide; acetophenone; In tetrahydrofuran; byproducts: KCl; using Schlenk, vac. line, glove box techniques in dry, O2 - free solvents; monohydride Ru complex, KO(t-Bu), acetophenone were mixed, THF added;mixt. stirred in atm. of N2 for 4 h; suspn. filtered; hexane added; mixt. stirred for 1 h; solid collected byfiltration; dried (vac.); recrystd. (benzene/hexane); elem. anal.;
DOI:10.1021/ja039396f

Reference yield:

: 60879-62-1
(trans-H***Cl, cis-P***P)[RuHCl(PPh₃)2(ethylenediamine)]

: 1333-74-0
hydrogen

: [RuHCl(PPh₃)2(ethylenediamine(-1H))]

: 229948-81-6,229962-76-9,494869-17-9
(trans-H***H, cis-P***P)[RuH₂(PPh₃)2(ethylenediamine)]

: 229948-81-6,229962-76-9,494869-17-9
(trans-P***P, cis-H***H)[RuH₂(PPh₃)2(ethylenediamine)]

: (cis-H***H, cis-P***P)[RuH₂(PPh₃)2(ethylenediamine)]

: [Ru2H2(PPh3)2(μ-eta.-2,η4-1,4-diazabutadiene)]

Guidance literature:: With potassium n-butoxide; In benzene-d6; byproducts: KCl, C4H9OH; using Schlenk, vac. line, glove box techniques in dry, O2 - free solvents; monohydride Ru complex and KO(t-Bu) were mixed in atm. of N2; C6D6 added; mixt. stirred for 3 min; soln. was frozen by cooling with liq. N2; H2 gas added; mixt. warmed to room temp.; not isolated; monitored by NMR spectroscopy;
DOI:10.1021/ja039396f