2,5-bis(trimethylstannyl)pyridine

Base Information

Chemical Name:2,5-bis(trimethylstannyl)pyridine
CAS No.:83674-67-3
Molecular Formula:C₁₁H₂₁NSn₂
Molecular Weight:404.714
Hs Code.:

Synonyms:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 2,5-bis(trimethylstannyl)pyridine

Chemical Property:

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Technology Process of 2,5-bis(trimethylstannyl)pyridine

There total 2 articles about 2,5-bis(trimethylstannyl)pyridine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

: 1256814-27-3
diethyl 5-chloropyridin-2-yl phosphate

: 1066-45-1
trimethyltin(IV)chloride

: 7440-23-5
sodium

: 83674-67-3
2,5-bis(trimethylstannyl)pyridine

: 59020-09-6
3-(trimethylstannyl)pyridine

: 13737-05-8
2-trimethylstannylpyridine

Guidance literature:: In ammonia; NH3 (liquid); Irradiation (UV/VIS); (inert atm.); addn. of 4.4 equiv. of sodium to soln. of 2.2 equiv. of tin compd. in liquid ammonia, addn. of 1 equiv. of pyridine deriv., stirring with irradiation for 30 min; quenching with methyl iodide, adn. of diethyl ether, evapn. of ammonia, treating with water, extn. (diethyl ether), washing with water and brine, drying over MgSO4, filtration, evapn., recrystn. (ethanol), NMR and MS;
DOI:10.1016/j.jorganchem.2010.08.032

Reference yield:

: 1256814-27-3
diethyl 5-chloropyridin-2-yl phosphate

: 1066-45-1
trimethyltin(IV)chloride

: 7440-23-5
sodium

: 83674-67-3
2,5-bis(trimethylstannyl)pyridine

: 1256814-30-8
diethyl 5-(trimethylstannyl)pyridin-2-yl phosphate

: 59020-09-6
3-(trimethylstannyl)pyridine

: 13737-05-8
2-trimethylstannylpyridine

Guidance literature:: With C₆H₄(NO₂)2; In ammonia; NH3 (liquid); (inert atm.); addn. of 4.4 equiv. of sodium to soln. of 2.2 equiv. of tin compd. in liquid ammonia, addn. of 1 equiv. of pyridine deriv. and p-dinitrobenzene, stirring for 60 min in dark;
DOI:10.1016/j.jorganchem.2010.08.032

Reference yield: 82.0%

: 83674-67-3
2,5-bis(trimethylstannyl)pyridine

: 13283-31-3
borane

: 7732-18-5
water

: 476460-50-1
pyridine-2,5-diboronic acid

: 1631-73-8
trimethylstannane

Guidance literature:: In tetrahydrofuran; (N2); addn. of a soln. of boron compd. in THF to a soln. of tin compd. in THF, keeping at room temp. for 1 h, refluxing for 3 h, evapn., addn. of Et2O and water; drying (MgSO4), evapn., recrystn. (water);
DOI:10.1021/om020163r