dicyano-bis-(1,10-phenanthroline)-iron(II) dihydrate

Base Information

• Chemical Name: dicyano-bis-(1,10-phenanthroline)-iron(II) dihydrate
• CAS No.: 15362-08-0
• Molecular Formula: C₂₆H₁₆FeN₆*2H₂O
• Molecular Weight: 504.331
• Mol file: 15362-08-0.mol

Synonyms:

Chemical Property of dicyano-bis-(1,10-phenanthroline)-iron(II) dihydrate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of dicyano-bis-(1,10-phenanthroline)-iron(II) dihydrate

There total 5 articles about dicyano-bis-(1,10-phenanthroline)-iron(II) dihydrate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

ferroin (14634-91-4) → dicyanobis(1,10-phenanthroline)iron(II) (14768-11-7,30872-77-6,80875-80-5,15334-30-2,15362-08-0)

Guidance literature:

With potassium cyanide; In water; Fe salt aq. soln. heating nearly boiling, aq. KCN adding at once, stirring, cooling to room temp., dark violet crystals collecting, drying in vacuo; identified by IR, UV spectra;

DOI:10.1021/om00065a010

Reference yield:

1,10-Phenanthroline (66-71-7) + pentacyanoaquaferrate(II) → ferroin (47836-89-5,14708-99-7,24324-38-7) + [Fe(1,10-phenanthroline)(CN)4](2-) (17455-55-9) + dicyanobis(1,10-phenanthroline)iron(II) (14768-11-7,30872-77-6,80875-80-5,15334-30-2,15362-08-0)

Guidance literature:

With sodium chloride; ascorbic acid; In water; Irradiation (UV/VIS); decompn. of aq. soln. of iron complex in the presence of o-phenanthroline (20-45°C, addn. of ascorbic acid, NaCl) under UV-irradiation; UV spect.; Kinetics;

DOI:10.1016/S0020-1693(00)87916-5

Reference yield:

1,10-Phenanthroline (66-71-7) + iron (7439-89-6) → dicyanobis(1,10-phenanthroline)iron(II) (14768-11-7,30872-77-6,80875-80-5,15334-30-2,15362-08-0)

Guidance literature:

With potassium cyanide; In methanol; water; Electrochem. Process; electrochem. oxidn. of Fe wire in MeOH-H2O (2:1) in presence of KCN andC12H8N2 (1:1 mol ratio);

upstream raw materials:

ferroin

cyanide^(1-)

ferroin

1,10-Phenanthroline

Downstream raw materials:

(C₁₂H₈N₂)2Fe{CNC(CH₃)2(CHCH₂CH₂CH(CH₃)CH₂C(O))}2⁽²⁺⁾*2BF₄^(1-)=(C₁₂H₈N₂)2Fe{CNC(CH₃)2(CHCH₂CH₂CH(CH₃)CH₂C(O))}2(BF₄)2

cis-bis(3-isocyano-cyclohexanone)bis(1,10-phenanthroline)iron(II)-bis(tetrafluoroborate)