(pR)-(η6-C6H4(CH3)(CHN(O)CH2C6H5))Cr(CO)3

Base Information

Chemical Name:(pR)-(η6-C6H4(CH3)(CHN(O)CH2C6H5))Cr(CO)3
CAS No.:805252-80-6
Molecular Formula:C₁₈H₁₅CrNO₄
Molecular Weight:361.317
Hs Code.:

Synonyms:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (pR)-(η6-C6H4(CH3)(CHN(O)CH2C6H5))Cr(CO)3

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Technology Process of (pR)-(η6-C6H4(CH3)(CHN(O)CH2C6H5))Cr(CO)3

There total 1 articles about (pR)-(η6-C6H4(CH3)(CHN(O)CH2C6H5))Cr(CO)3 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

: 33152-65-7,32734-21-7,33152-66-8
ortho-tolualdehyde chromium tricarbonyl

: 622-30-0
N-benzyl hydroxylalmine

: 805252-80-6,804562-52-5,1220995-24-3,1220995-26-5
Cr(CO)3(C₆H₄(CH₃)CHN(O)CH₂C₆H₅)

Guidance literature:: With MgSO₄; In dichloromethane; refluxed for 15 h;
DOI:10.1039/b405406g

Reference yield: 96.0%

: 805252-80-6,804562-52-5,1220995-24-3,1220995-26-5
Cr(CO)3(C₆H₄(CH₃)CHN(O)CH₂C₆H₅)

: 630-19-3
pivalaldehyde

: 805252-78-2,804562-64-9
(C₆H₄(CH₃)CH(CH(OH)C(CH₃)3)N(OH)CH₂C₆H₅)Cr(CO)3

Guidance literature:: With SmI₂; Na₂S₂O₃; NaHCO₃; In tetrahydrofuran; soln. of nitrone and 1 equiv. pivalaldehyde in THF cooled to -78°C, 2 equiv. soln. SmI2 in THF added drop by drop, mixt. stirred at - 78°C for 30 min before quenched by satd. soln. of Na2S2O3 and NaHCO3; extn. (AcOEt), washing (satd. aq. NaCl), drying (MgSO4), concn. in vacuo, washing (cyclohexane), 1H NMR anal.;
DOI:10.1039/b405406g

Reference yield: 95.0%

: 805252-80-6,804562-52-5,1220995-24-3,1220995-26-5
Cr(CO)3(C₆H₄(CH₃)CHN(O)CH₂C₆H₅)

: 67-64-1
acetone

: 804562-58-1,805252-81-7,805252-75-9,805252-82-8
rac-(η6-C6H4(Me)CH(N(OH)CH2C6H5)C(Me)2OH)chromium tricarbonyl

Guidance literature:: With SmI₂; Na₂S₂O₃; NaHCO₃; In tetrahydrofuran; soln. of nitrone and 1 equiv. acetone in THF cooled to -78°C, 2 equiv. soln. SmI2 in THF added drop by drop, mixt. stirred at - 78°C for 30 min before quenched by satd. soln. of Na2S2O3 and NaHCO3; extn. (AcOEt), washing (satd. aq. NaCl), drying (MgSO4), concn. in vacuo, washing (cyclohexane), 1H NMR anal.;
DOI:10.1039/b405406g