2-Pyridinylthio

Base Information

• Chemical Name: 2-Pyridinylthio
• CAS No.: 117658-12-5
• Molecular Formula: C₅H₄NS
• Molecular Weight: 110.159
• Mol file: 117658-12-5.mol

Synonyms:

Chemical Property of 2-Pyridinylthio

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 2-Pyridinylthio

There total 8 articles about 2-Pyridinylthio which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(2,2-diphenylcyclobutyl) acetic acid 2-thioxo-2H-pyridin-1-yl ester (286850-88-2) → pyridine-2-ylsulfanyl radical (117658-12-5) + 2,2-diphenylcyclobutylcarbinyl radical (286850-97-3)

Guidance literature:

In tetrahydrofuran; at -20 ℃; Title compound not separated from byproducts.; Photolysis;

DOI:10.1021/jo000095n

Reference yield:

3-(diethoxy-phosphoryloxy)-8-(2,2-diphenyl-cyclopropyl)-2-methoxy-2-methyl-oct-7-enoic acid 2-thioxo-2H-pyridin-1-yl ester → pyridine-2-ylsulfanyl radical (117658-12-5) + C24H28O(1+)

Guidance literature:

In acetonitrile; at 21 ℃; Further Variations:; Solvents; Kinetics; Product distribution; Flash photolysis;

DOI:10.1021/ja015639x

Reference yield:

3-(diethoxy-phosphoryloxy)-10-(2,2-diphenyl-cyclopropyl)-2-methoxy-2-methyl-dec-9-enoic acid 2-thioxo-2H-pyridin-1-yl ester → pyridine-2-ylsulfanyl radical (117658-12-5) + C25H30O(1+)

Guidance literature:

In 2,2,2-trifluoroethanol; acetonitrile; at 21 ℃; Further Variations:; Solvents; Kinetics; Product distribution; Flash photolysis;

DOI:10.1021/ja015639x

upstream raw materials:

(2,2-diphenylcyclobutyl) acetic acid 2-thioxo-2H-pyridin-1-yl ester

(1H)-2-thioxo-1-pyridyl 3-methanesulfonyloxy-2-methoxy-2-methyl-3-phenylpropionate

(1H)-2-thioxo-1-pyridyl 9,9-diphenyl-3-methanesulfonyloxy-2-methoxy-2-methyl-8-nonenoate

(1H)-2-thioxo-1-pyridyl 3-(diethylphosphatoxy)-2,2-dimethyldihydro-p-methoxycinnamate