9,9-Bis(4-methoxyphenyl)-9h-fluorene

Base Information

• Chemical Name: 9,9-Bis(4-methoxyphenyl)-9h-fluorene
• CAS No.: 117766-40-2
• Molecular Formula: C27H22O2
• Molecular Weight: 378.47
• DSSTox Substance ID: DTXSID10472557
• Nikkaji Number: J1.559.625B
• Wikidata: Q82301533
• Mol file: 117766-40-2.mol

Synonyms:9,9-bis(4-methoxyphenyl)-9h-fluorene;117766-40-2;9H-Fluorene, 9,9-bis(4-methoxyphenyl)-;9,9-bis(4-methoxyphenyl)fluorene;SCHEMBL1702667;DTXSID10472557;BYDIWLYAWBNCAQ-UHFFFAOYSA-N;MFCD00192781;AKOS037621703;BS-44133;B5617;T70126

Chemical Property of 9,9-Bis(4-methoxyphenyl)-9h-fluorene

Chemical Property:

• XLogP3: 6.6
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 4
• Exact Mass: 378.161979940
• Heavy Atom Count: 29
• Complexity: 481

Purity/Quality:

97% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: COC1=CC=C(C=C1)C2(C3=CC=CC=C3C4=CC=CC=C42)C5=CC=C(C=C5)OC

Technology Process of 9,9-Bis(4-methoxyphenyl)-9h-fluorene

There total 7 articles about 9,9-Bis(4-methoxyphenyl)-9h-fluorene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

3-(biphenyl-2-yl)-1-phenylprop-2-yn-1-one (1616859-93-8) + methoxybenzene (100-66-3) → Fluorene-9,9-bisphenol dimethyl ether (117766-40-2)

Guidance literature:

With trifluorormethanesulfonic acid; at 100 ℃; for 1h; Sealed tube; Inert atmosphere;

DOI:10.1039/c8cc05484c

Reference yield: 79.0%

9,9-bis(4-hydroxyphenyl)fluorene (3236-71-3) + methyl iodide (74-88-4) → Fluorene-9,9-bisphenol dimethyl ether (117766-40-2)

Guidance literature:

With potassium carbonate; In N,N-dimethyl-formamide; at 10 ℃;

Reference yield: 60.0%

9-fluorenone (486-25-9,952573-42-1) + methoxybenzene (100-66-3) → Fluorene-9,9-bisphenol dimethyl ether (117766-40-2)

Guidance literature:

With sulfuric acid; mercaptoacetic acid; In acetic acid; at 20 ℃; for 96h;

DOI:10.1039/b008451o

upstream raw materials:

Biphenyl-2-yl-bis-(4-methoxy-phenyl)-methanol

9-fluorenone

methoxybenzene

bis(p-methoxyphenyl)methanone

Downstream raw materials:

9,9-bis(4-hydroxyphenyl)fluorene