⁽⁹⁹⁾Tc(2,3,5,6-tetramethylbenzenethiolate)3(CO)2

Base Information

Chemical Name:⁽⁹⁹⁾Tc(2,3,5,6-tetramethylbenzenethiolate)3(CO)2
CAS No.:113584-57-9
Molecular Formula:C₃₂H₃₉O₂S₃Tc
Molecular Weight:650.858
Hs Code.:

<sup>(99)</sup>Tc(2,3,5,6-tetramethylbenzenethiolate)3(CO)2

Synonyms:

Suppliers and Price of ⁽⁹⁹⁾Tc(2,3,5,6-tetramethylbenzenethiolate)3(CO)2

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of ⁽⁹⁹⁾Tc(2,3,5,6-tetramethylbenzenethiolate)3(CO)2

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of ⁽⁹⁹⁾Tc(2,3,5,6-tetramethylbenzenethiolate)3(CO)2

There total 1 articles about ⁽⁹⁹⁾Tc(2,3,5,6-tetramethylbenzenethiolate)3(CO)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 64.0%

: 113584-53-5
⁽⁹⁹⁾Tc(2,3,5,6-tetramethylbenzenethiolate)3(CH₃CN)2

: 201230-82-2
carbon monoxide

: 113584-57-9
⁽⁹⁹⁾Tc(2,3,5,6-tetramethylbenzenethiolate)3(CO)2

Guidance literature:: In dichloromethane; CO is bubbled through a soln. of Tc(tmbt)3(MeCN)2 overnight, evapg. all the solvent.; Column chromy. (silica gel, CHCl3, under CO pressure), addn. of MeOH to the major fraction, removing the CHCl3 with a stream of CO, crystals are collected, washed with methanol, dried in vac.;

Reference yield: 90.0%

: 110-86-1
pyridine

: 113584-57-9
⁽⁹⁹⁾Tc(2,3,5,6-tetramethylbenzenethiolate)3(CO)2

: 113584-61-5
⁽⁹⁹⁾Tc(2,3,5,6-tetramethylbenzenethiolate)3(CO)(pyridine)

Guidance literature:: In pyridine; Soln. of Tc(tmbt)3(CO)2 in pyridine is set to reflux for 3 h, a red soln. results.; Soln. is cooled, volume is reduced to an oil, column chromy. (silica gel, CHCl3), addn. of MeOH to the major orange fraction, CHCl3 is allowed to evap., crystals are collected, washed with MeOH and dried in vac.;

Reference yield: 62.0%

: 113584-57-9
⁽⁹⁹⁾Tc(2,3,5,6-tetramethylbenzenethiolate)3(CO)2

: 75-05-8,26809-02-9
acetonitrile

: 113584-59-1
⁽⁹⁹⁾Tc(2,3,5,6-tetramethylbenzenethiolate)3(CO)(CH₃CN)

Guidance literature:: In acetonitrile; Soln. of Tc(tmbt)3(CO)2 in MeCN is allowed to reflux for 3 d.; Evapn., column chromy. (silica gel, CHCl3), recrystn. from hot MeCN.;