Tetrasilane, 1,1,1,4,4,4-hexamethyl-2,3-diphenyl-2,3-bis(trimethylsilyl)-

Base Information

• Chemical Name: Tetrasilane, 1,1,1,4,4,4-hexamethyl-2,3-diphenyl-2,3-bis(trimethylsilyl)-
• CAS No.: 118714-41-3
• Molecular Formula: C24H46Si6
• Molecular Weight: 503.142
• Mol file: 118714-41-3.mol

Synonyms:

Chemical Property of Tetrasilane, 1,1,1,4,4,4-hexamethyl-2,3-diphenyl-2,3-bis(trimethylsilyl)-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Tetrasilane, 1,1,1,4,4,4-hexamethyl-2,3-diphenyl-2,3-bis(trimethylsilyl)-

There total 4 articles about Tetrasilane, 1,1,1,4,4,4-hexamethyl-2,3-diphenyl-2,3-bis(trimethylsilyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

chlorobis(trimethylsilyl)phenylsilane (127348-36-1) → 1,1,1,4,4,4-hexamethyl-2,3-diphenyl-2,3-bis(trimethylsilyl)-n-tetrasilan (118714-41-3)

Guidance literature:

With sodium; In toluene; for 8h; Heating;

DOI:10.1016/S0022-328X(98)00422-7

Reference yield: 80.0%

C13H23F3O3SSi3 (136839-76-4) → 1,1,1,4,4,4-hexamethyl-2,3-diphenyl-2,3-bis(trimethylsilyl)-n-tetrasilan (118714-41-3)

Guidance literature:

With lithium; In tetrahydrofuran; for 12h; Heating;

DOI:10.1016/S0022-328X(97)00127-7

Reference yield:

1,1,1,3,3,3-hexamethyl-2,2-diphenyltrisilane (18549-83-2) → 1,1,1,4,4,4-hexamethyl-2,3-diphenyl-2,3-bis(trimethylsilyl)-n-tetrasilan (118714-41-3)

Guidance literature:

Multi-step reaction with 2 steps

1: 66 percent / sublimed aluminium trichloride, hydrogen chloride gas / benzene / 14 h

2: 80 percent / sodium / toluene / 8 h / Heating

With hydrogenchloride; aluminium trichloride; sodium; In toluene; benzene;

DOI:10.1016/S0022-328X(98)00422-7

upstream raw materials:

chlorobis(trimethylsilyl)phenylsilane

C₁₃H₂₃F₃O₃SSi₃

chloro-trimethyl-silane

Phenyltrichlorosilane

Refernces

• 1、 Kusukawa, Takahiro,Ando, Wataru. "Photochemical functionalizations of C60 with phenylpolysilanes". . p. 11 - 22. Retrieved 2007/10/03.