[Mo2(C5H5)2(μ-κ1:η2-C(O)Ph)(μ-PCy2)(NO)2]

Base Information

• Chemical Name: [Mo2(C5H5)2(μ-κ1:η2-C(O)Ph)(μ-PCy2)(NO)2]
• CAS No.: 1195978-67-6
• Molecular Formula: C₂₉H₃₇Mo₂N₂O₃P
• Molecular Weight: 684.478
• Mol file: 1195978-67-6.mol

Synonyms:

Chemical Property of [Mo2(C5H5)2(μ-κ1:η2-C(O)Ph)(μ-PCy2)(NO)2]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Mo2(C5H5)2(μ-κ1:η2-C(O)Ph)(μ-PCy2)(NO)2]

There total 3 articles about [Mo2(C5H5)2(μ-κ1:η2-C(O)Ph)(μ-PCy2)(NO)2] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

[Mo2(C5H5)2(Ph)(μ-PCy2)(CO)(NO)2] (1195978-66-5) → [Mo2(C5H5)2(μ-κ1:η2-C(O)Ph)(μ-PCy2)(NO)2] (1195978-67-6)

Guidance literature:

In toluene; (N2); std. Schlenk technique; soln. of Mo complex in toluene was stirredat 343 K for 1.5 h; evapd. (vac.); dissolved in CH2Cl2; chromd. (alumina, CH2Cl2/petroleum ether, 1/2, 288 K); evapd. (vac.);

DOI:10.1021/om9006856

Reference yield: 70.0%

[Mo2(C5H5)2(μ-Ph)(μ-PCy2)(CO)2] (960303-59-7) + nitrogen(II) oxide (10102-43-9) → [Mo2(C5H5)2(μ-κ1:η2-C(O)Ph)(μ-PCy2)(NO)2] (1195978-67-6)

Guidance literature:

In toluene; (N2); std. Schlenk technique; NO (2000 ppm in N2) was bubbled through stirred soln. of Mo complex in toluene at room temp. for 16 h; stirred under reflux for 1 h; evapd. (vac.); dissolved in CH2Cl2; chromd. (alumina, CH2Cl2/petroleum ether, 1/2, 288 K); evapd. (vac.);

DOI:10.1021/om9006856

Reference yield: 48.0%

[Mo2(C5H5)2(μ-Ph)(μ-PCy2)(CO)2] (960303-59-7) + nitrogen(II) oxide (10102-43-9) → [Mo2(C5H5)2(μ-κ1:η2-Ph)(μ-PCy2)(NO)2] (1195978-59-6) + [Mo2(C5H5)2(μ-κ1:η2-C(O)Ph)(μ-PCy2)(NO)2] (1195978-67-6) + [Mo2(C5H5)2(Ph)(μ-PCy2)(CO)(NO)2] (1195978-66-5) + [Mo2(C5H5)2(C(O)Ph)(μ-PCy2)(CO)(NO)2] (1195978-57-4)

Guidance literature:

In toluene; (N2); std. Schlenk technique; NO (2000 ppm in N2) was bubbled through stirred soln. of Mo complex in toluene at room temp. for 16 h; evapd. (vac.); dissolved in CH2Cl2; chromd. (alumina, CH2Cl2/petroleum ether, 1/4, 1/2, 1/1, 288 K); evapd. (vac.); recrystd. by diffusion of petroleum ether into CH2Cl2 soln. at 253 K; elem. anal.;

DOI:10.1021/om9006856

upstream raw materials:

[Mo2(C5H5)2(μ-Ph)(μ-PCy2)(CO)2]

nitrogen(II) oxide

[Mo2(C5H5)2(Ph)(μ-PCy2)(CO)(NO)2]