[Mo2(C5H5)2(μ-Ph)(μ-PCy2)(CO)2]

Base Information

• Chemical Name: [Mo2(C5H5)2(μ-Ph)(μ-PCy2)(CO)2]
• CAS No.: 960303-59-7
• Molecular Formula: C₃₀H₃₇Mo₂O₂P
• Molecular Weight: 652.476
• Mol file: 960303-59-7.mol

Synonyms:

Chemical Property of [Mo2(C5H5)2(μ-Ph)(μ-PCy2)(CO)2]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Mo2(C5H5)2(μ-Ph)(μ-PCy2)(CO)2]

There total 2 articles about [Mo2(C5H5)2(μ-Ph)(μ-PCy2)(CO)2] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

[Mo2(η5-cyclopentadienyl)2(μ-H)(μ-PCy2)(CO)2] (537683-54-8) + triphenyllead(IV) chloride (1153-06-6) + lithium triethylborohydride (22560-16-3) → [Mo2(C5H5)2(μ-Ph)(μ-PCy2)(CO)2] (960303-59-7)

Guidance literature:

In dichloromethane; (N2); Mo complex reacted with Li salt in THF for 5 min at room temp., evapd. (vac.), CH2Cl2 added, (C6H5)3PbCl added, stirred for 4 h; evapd. (vac.), chromd. (alumina, CH2Cl2/petroleum ether), solvent-removed; elem. anal.;

DOI:10.1021/om7007265

Reference yield:

Li[Mo2Cp2(μ-PCy2)(μ-CO)2] (537683-53-7) + triphenyllead(IV) chloride (1153-06-6) → [Mo2(μ-Cl)(η5-cyclopentadienyl)2(μ-dicyclohexylphosphide)(carbonyl)2] (537683-52-6) + [Mo2(C5H5)2(μ-Ph)(μ-PCy2)(CO)2] (960303-59-7)

Guidance literature:

In tetrahydrofuran; (N2);

DOI:10.1021/om7007265

Reference yield: 70.0%

[Mo2(C5H5)2(μ-Ph)(μ-PCy2)(CO)2] (960303-59-7) + nitrogen(II) oxide (10102-43-9) → [Mo2(C5H5)2(μ-κ1:η2-C(O)Ph)(μ-PCy2)(NO)2] (1195978-67-6)

Guidance literature:

In toluene; (N2); std. Schlenk technique; NO (2000 ppm in N2) was bubbled through stirred soln. of Mo complex in toluene at room temp. for 16 h; stirred under reflux for 1 h; evapd. (vac.); dissolved in CH2Cl2; chromd. (alumina, CH2Cl2/petroleum ether, 1/2, 288 K); evapd. (vac.);

DOI:10.1021/om9006856

upstream raw materials:

[Mo2(η5-cyclopentadienyl)2(μ-H)(μ-PCy2)(CO)2]

triphenyllead(IV) chloride

lithium triethylborohydride

Li[Mo₂Cp₂(μ-PCy₂)(μ-CO)₂]

Downstream raw materials:

[Mo2(C5H5)(μ-PCy2)(CO)7]

[Mo2(C5H5)(η5-C5H4Ph)(μ-H)(μ-PCy2)(CO)4]

[Mo2(C5H5)2(μ-κ1:η2-Ph)(μ-PCy2)(NO)2]

[Mo2(C5H5)2(μ-κ1:η2-C(O)Ph)(μ-PCy2)(NO)2]