Au(SC₆F₅)(P(C₆H₅)2CH₂CH₂C₅H₄N)

Base Information

• Chemical Name: Au(SC₆F₅)(P(C₆H₅)2CH₂CH₂C₅H₄N)
• CAS No.: 1331734-82-7
• Molecular Formula: C₂₅H₁₈AuF₅NPS
• Molecular Weight: 687.423
• Mol file: 1331734-82-7.mol

Synonyms:

Chemical Property of Au(SC₆F₅)(P(C₆H₅)2CH₂CH₂C₅H₄N)

Chemical Property:

Purity/Quality:

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Useful:

Technology Process of Au(SC₆F₅)(P(C₆H₅)2CH₂CH₂C₅H₄N)

There total 1 articles about Au(SC₆F₅)(P(C₆H₅)2CH₂CH₂C₅H₄N) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 49.0%

pentafluorophenylthiol (771-62-0) + (2-(2-(diphenylphosphino)ethyl)pyridyl)gold(I) chloride (937172-17-3) → Au(SC6F5)(P(C6H5)2CH2CH2C5H4N) (1331734-82-7)

Guidance literature:

With potassium carbonate; In dichloromethane; under N2; HSC6F5 and K2CO3 added to soln. of Au complex in CH2Cl2; stirred at room temp. for 2 h; filtered through Celite; soln. concd.; Et2O added; solid collected; elem. anal.;

DOI:10.1021/ic201245q

Reference yield: 65.0%

tetrakis(actonitrile)copper(I) hexafluorophosphate (64443-05-6) + Au(SC6F5)(P(C6H5)2CH2CH2C5H4N) (1331734-82-7) → [Au2Cu2(μ-SC6F5)2(μ-PPh2CH2CH2C5H4N)2(NCMe)2](PF6)2

Guidance literature:

In dichloromethane; under N2; Cu complex added to soln. of Au complex in CH2Cl2; stirred for30 min; soln. concd.; hexane added; solid collected; elem. anal.;

DOI:10.1021/ic201245q

Reference yield: 62.0%

Au(SC6F5)(P(C6H5)2CH2CH2C5H4N) (1331734-82-7) + silver trifluoromethanesulfonate (2923-28-6) → [Ag2Au2(μ-SC6F5)2(μ-PPh2CH2CH2C5H4N)2(OSO2CF3)2] (1331734-89-4)

Guidance literature:

In dichloromethane; Ag salt added to soln. of Au complex in CH2Cl2; stirred for 20 min; filtered through Celite; soln. concd.; hexane added; solid collected; elem. anal.;

DOI:10.1021/ic201245q

upstream raw materials:

pentafluorophenylthiol

(2-(2-(diphenylphosphino)ethyl)pyridyl)gold(I) chloride

Downstream raw materials:

[Ag2Au2(μ-SC6F5)2(μ-PPh2CH2CH2C5H4N)2(OSO2CF3)2]