FeCo2(CO)9(μ3-PhCCPh)

Base Information

Chemical Name:FeCo2(CO)9(μ3-PhCCPh)
CAS No.:86972-73-8
Molecular Formula:C₂₃H₁₀Co₂FeO₉
Molecular Weight:604.16
Hs Code.:

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Chemical Property of FeCo2(CO)9(μ3-PhCCPh)

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Technology Process of FeCo2(CO)9(μ3-PhCCPh)

There total 1 articles about FeCo2(CO)9(μ3-PhCCPh) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 15226-74-1,61091-28-9,61117-58-6
dicobalt octacarbonyl

: 15321-51-4
diiron nonacarbonyl

: 501-65-5
diphenyl acetylene

: 86972-73-8
FeCo2(CO)9(μ3-PhCCPh)

Guidance literature:: In hexane; addn. of the alkyne in hexane to Co2(CO)8 in hexane at -78°C, stirring for 4 h without cooling, filtration, washing with hexane, addn. of THF and Fe2(CO)9 (4 times, in 1 h interval), stirring overnight; evapn. (vac.), dissolving in hexane, filtration and cooling to -30°C (2 crops);

Reference yield: 14.0%

: 1277-43-6,78206-33-4
cobaltocene

: 86972-73-8
FeCo2(CO)9(μ3-PhCCPh)

: 14515-69-6
(CO)6Co₂(C₂Ph₂)

: 126329-13-3
FeCo(CO)6{μ-C(C6H5)C(C6H5)C(CH3)O}

Guidance literature:: With CH₃I; In tetrahydrofuran; soln. of Cp2Co/THF added to soln. of Co2Fe-cluster/THF at -78°C, warmed to room temp. over period of 20 min (formation of radical anion intermediate (IR)), excess MeI added, stirred (40°C, 15h); evapn. (vac.), benzene and H3PO4 added to residue, extn. (benzene) until organic phase colorless, concn. of combined benzene extracts, addn. hexane, chromy. (silica gel, hexane/benzene), evapn. (vac.), cooled to -30°C;

Reference yield: 7.0%

: 1277-43-6,78206-33-4
cobaltocene

: 86972-73-8
FeCo2(CO)9(μ3-PhCCPh)

: 75-03-6
ethyl iodide

: 14515-69-6
(CO)6Co₂(C₂Ph₂)

: 126329-14-4
FeCo(CO)6{μ-C(C6H5)C(C6H5)C(C2H5)O}

Guidance literature:: In dichloromethane; soln. of Cp2Co/CH2Cl2 added to soln. of Co2Fe-cluster/CH2Cl2 at -78°C, warmed to room temp. over period of 20 min (formation of radical anion intermediate (IR)), excess C2H5I added, stirred (40°C, 15h); evapn. (vac.), benzene and H3PO4 added to residue, extn. (benzene) until organic phase colorless, concn. of combined benzene extracts, addn. hexane, chromy. (silica gel, hexane/benzene), evapn. (vac.), cooled to -30°C;