Technology Process of Benzenethiol, 2,2'-(phenylphosphinidene)bis-
There total 1 articles about Benzenethiol, 2,2'-(phenylphosphinidene)bis- which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
n-butyllithium; N,N,N,N,-tetramethylethylenediamine;
Yield given. Multistep reaction;
1.) hexane, 2.) THF, -78 deg C to room temp., overnight;
DOI:10.1021/ja00188a071
- Guidance literature:
-
In
acetonitrile;
byproducts: H2; Electrolysis; N2-atmosphere; anodic oxidation of metal (Pt-cathode, in presence of Me4NClO4, 20 V, 10 mA, 2 h; pptn.); washing (MeCN, ether), drying (vac.); elem. anal.;
DOI:10.1021/ic981405b
- Guidance literature:
-
With
sodium ethoxide;
In
ethanol;
to a suspn. of phosphine in ethanol was added a NaOC2H5, after 15 min ofstirring SnCl2(CH3)2 was added, stirred for 4 h; ppt. was filtered off, washed with ethanol, dried in vac.; elem. anal.;
DOI:10.1016/S0022-328X(00)00936-0
