Benzenethiol, 2,2'-(phenylphosphinidene)bis-

Base Information

Chemical Name:Benzenethiol, 2,2'-(phenylphosphinidene)bis-
CAS No.:119327-18-3
Molecular Formula:C18H15PS2
Molecular Weight:326.423
Hs Code.:
DSSTox Substance ID:DTXSID00476640
Nikkaji Number:J1.078.709B

Synonyms:Benzenethiol, 2,2'-(phenylphosphinidene)bis-;119327-18-3;SCHEMBL19696748;DTXSID00476640

Suppliers and Price of Benzenethiol, 2,2'-(phenylphosphinidene)bis-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Benzenethiol, 2,2'-(phenylphosphinidene)bis-

Chemical Property:

XLogP3:4.9
Hydrogen Bond Donor Count:2
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:3
Exact Mass:326.03527982
Heavy Atom Count:21
Complexity:294

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1=CC=C(C=C1)P(C2=CC=CC=C2S)C3=CC=CC=C3S

Technology Process of Benzenethiol, 2,2'-(phenylphosphinidene)bis-

There total 1 articles about Benzenethiol, 2,2'-(phenylphosphinidene)bis- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 108-98-5
thiophenol

: 644-97-3
Dichlorophenylphosphine

: 119327-18-3
bis(phenyl-2-thiol)phenylphosphine

Guidance literature:: With n-butyllithium; N,N,N,N,-tetramethylethylenediamine; Yield given. Multistep reaction; 1.) hexane, 2.) THF, -78 deg C to room temp., overnight;
DOI:10.1021/ja00188a071

Reference yield: 94.0%

: 119327-18-3
bis(phenyl-2-thiol)phenylphosphine

: 7440-66-6
zinc

: 237762-65-1
[Zn(PhP(C₆H₄S-2)2)]

Guidance literature:: In acetonitrile; byproducts: H2; Electrolysis; N2-atmosphere; anodic oxidation of metal (Pt-cathode, in presence of Me4NClO4, 20 V, 10 mA, 2 h; pptn.); washing (MeCN, ether), drying (vac.); elem. anal.;
DOI:10.1021/ic981405b

Reference yield: 92.0%

: 753-73-1
dimethyltin dichloride

: 119327-18-3
bis(phenyl-2-thiol)phenylphosphine

: Sn(CH₃)2(SC₆H₄)2P(C₆H₅)

Guidance literature:: With sodium ethoxide; In ethanol; to a suspn. of phosphine in ethanol was added a NaOC2H5, after 15 min ofstirring SnCl2(CH3)2 was added, stirred for 4 h; ppt. was filtered off, washed with ethanol, dried in vac.; elem. anal.;
DOI:10.1016/S0022-328X(00)00936-0