RuCl(P(CH₃)3)(P(CH₂C₆H₅)3)(C₁₅H₁₁N₃)⁽¹⁺⁾*ClO₄^(1-) = [RuCl(P(CH₃)3)(P(CH₂C₆H₅)3)(C₁₅H₁₁N₃)]ClO₄

Base Information

• Chemical Name: RuCl(P(CH₃)3)(P(CH₂C₆H₅)3)(C₁₅H₁₁N₃)⁽¹⁺⁾*ClO₄^(1-) = [RuCl(P(CH₃)3)(P(CH₂C₆H₅)3)(C₁₅H₁₁N₃)]ClO₄
• CAS No.: 176731-15-0
• Molecular Formula: C₃₉H₄₁ClN₃P₂Ru*ClO₄
• Molecular Weight: 849.696
• Mol file: 176731-15-0.mol

Synonyms:

Chemical Property of RuCl(P(CH₃)3)(P(CH₂C₆H₅)3)(C₁₅H₁₁N₃)⁽¹⁺⁾*ClO₄^(1-) = [RuCl(P(CH₃)3)(P(CH₂C₆H₅)3)(C₁₅H₁₁N₃)]ClO₄

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of RuCl(P(CH₃)3)(P(CH₂C₆H₅)3)(C₁₅H₁₁N₃)⁽¹⁺⁾*ClO₄^(1-) = [RuCl(P(CH₃)3)(P(CH₂C₆H₅)3)(C₁₅H₁₁N₃)]ClO₄

There total 1 articles about RuCl(P(CH₃)3)(P(CH₂C₆H₅)3)(C₁₅H₁₁N₃)⁽¹⁺⁾*ClO₄^(1-) = [RuCl(P(CH₃)3)(P(CH₂C₆H₅)3)(C₁₅H₁₁N₃)]ClO₄ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

cis-dichloro-trimethylphosphine-(2,2':6',2''-terpyridine)ruthenium(II) (126294-76-6,126451-69-2) + sodium perchlorate + tribenzylphosphine (7650-89-7) → RuCl(P(CH3)3)(P(CH2C6H5)3)(C15H11N3)(1+)*ClO4(1-) = [RuCl(P(CH3)3)(P(CH2C6H5)3)(C15H11N3)]ClO4 (176731-15-0)

Guidance literature:

In ethanol; water; acetone; (inert atmosphere); addn. of P(CH2C6H5)3 to the Ru complex in acetone/EtOH, stirring (room temp., 3 h), evapn. (rotavapor), dissoln. (EtOH/H2O),addn. of aq. NaClO4; pptn. on concn.; elem. anal.;

DOI:10.1039/DT9960001463

Reference yield: 92.0%

RuCl(P(CH3)3)(P(CH2C6H5)3)(C15H11N3)(1+)*ClO4(1-) = [RuCl(P(CH3)3)(P(CH2C6H5)3)(C15H11N3)]ClO4 (176731-15-0) + sodium perchlorate + sodium nitrite (7632-00-0) → Ru(NO2)(P(CH3)3)(P(CH2C6H5)3)(C15H11N3)(1+)*ClO4(1-) = [Ru(NO2)(P(CH3)3)(P(CH2C6H5)3)(C15H11N3)]ClO4

Guidance literature:

In ethanol; water; (N2); refluxing the Ru complex and NaNO2 in H2O/EtOH for 3 h, after cooling to room temp. addn. of excess aq. NaClO4; chromy. (alumina; toluene/MeCN), concn.; elem. anal.;

DOI:10.1039/DT9960001463

upstream raw materials:

cis-dichloro-trimethylphosphine-(2,2':6',2''-terpyridine)ruthenium(II)

tribenzylphosphine